|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM369177304 |
| 003 |
DE-627 |
| 005 |
20240608002928.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
240302s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202313835
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1432.xml
|
| 035 |
|
|
|a (DE-627)NLM369177304
|
| 035 |
|
|
|a (NLM)38427844
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Zhang, Longhai
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Rational Design of Multinary Metal Chalcogenide Bi0.4Sb1.6Te3 Nanocrystals for Efficient Potassium Storage
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 07.06.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2024 Wiley‐VCH GmbH.
|
| 520 |
|
|
|a Multinary metal chalcogenides hold considerable promise for high-energy potassium storage due to their numerous redox reactions. However, challenges arise from issues such as volume expansion and sluggish kinetics. Here, a design featuring a layered ternary Bi0.4Sb1.6Te3 anchored on graphene layers as a composite anode, where Bi atoms act as a lattice softening agent on Sb, is presented. Benefiting from the lattice arrangement in Bi0.4Sb1.6Te3 and structure, Bi0.4Sb1.6Te3/graphene exhibits a mitigated expansion of 28% during the potassiation/depotassiation process and demonstrates facile K+ ion transfer kinetics, enabling long-term durability of 500 cycles at various high rates. Operando synchrotron diffraction patterns and spectroscopies including in situ Raman, ex situ adsorption, and X-ray photoelectron reveal multiple conversion and alloying/dealloying reactions for potassium storage at the atomic level. In addition, both theoretical calculations and electrochemical examinations elucidate the K+ migration pathways and indicate a reduction in energy barriers within Bi0.4Sb1.6Te3/graphene, thereby suggesting enhanced diffusion kinetics for K+. These findings provide insight in the design of durable high-energy multinary tellurides for potassium storage
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Bi0.4Sb1.6Te3 anode
|
| 650 |
|
4 |
|a multinary metal chalcogenide
|
| 650 |
|
4 |
|a potassium ion batteries
|
| 650 |
|
4 |
|a synergetic effect
|
| 700 |
1 |
|
|a Liu, Jiatu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhai, Yunming
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Shilin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Wei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Guanjie
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Sun, Liang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Hongbao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Qi, Shuo
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chen, Shuangqiang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Rui
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ma, Quanwei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Just, Justus
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Chaofeng
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 23 vom: 28. Juni, Seite e2313835
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:23
|g day:28
|g month:06
|g pages:e2313835
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202313835
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 23
|b 28
|c 06
|h e2313835
|