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240229s2024 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.4c00091
|2 doi
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|a pubmed24n1324.xml
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|a DE-627
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|a eng
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|a Ma, Yujie
|e verfasserin
|4 aut
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|a SnS/SnS2 Heterostructures Embedded in Hierarchical Porous Carbon as Polysulfides Immobilizer for High-Performance Lithium-Sulfur Batteries
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|c 2024
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 12.03.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Driven by the strong adsorptive and catalytic ability of metal sulfides for soluble polysulfides, it is considered as a potential mediator to resolve the problems of shuttle effect and slow reaction kinetics of polysulfides in lithium-sulfur (Li-S) batteries. However, their further development is limited by poor electrical conductivity and bad long-term durability. Herein, one type of new catalyst composed of SnS/SnS2 heterostructures on hierarchical porous carbon (denoted as SnS/SnS2-HPC) by a simple hydrothermal method is reported and used as an interlayer coating on the conventional separator for blocking polysulfides. The SnS/SnS2-HPC integrates the advantages of a porous conductive network for promoting the transport of electrons and an enhanced electrocatalyst for accelerating polysulfides conversion. As a result, such a cell coupled with a SnS/SnS2-HPC interlayer exhibits a long-term lifespan of 1200 cycles. This work provides a new cell configuration by using heterostructures with a built-in electric field formed from a p-n heterojunction to improve the performance of Li-S batteries
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|a Journal Article
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|a Li, Fengqi
|e verfasserin
|4 aut
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|a Ji, Hurong
|e verfasserin
|4 aut
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|a Wu, Hao
|e verfasserin
|4 aut
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|a Wang, Biao
|e verfasserin
|4 aut
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|a Ren, Yilun
|e verfasserin
|4 aut
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|a Cao, Jiangdong
|e verfasserin
|4 aut
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|a Cao, Xueyu
|e verfasserin
|4 aut
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|a Ding, Feng
|e verfasserin
|4 aut
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|a Lu, Jiahao
|e verfasserin
|4 aut
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|a Yang, Xiping
|e verfasserin
|4 aut
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|a Meng, Xiangkang
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 40(2024), 10 vom: 12. März, Seite 5527-5534
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:40
|g year:2024
|g number:10
|g day:12
|g month:03
|g pages:5527-5534
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|u http://dx.doi.org/10.1021/acs.langmuir.4c00091
|3 Volltext
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