|
|
|
|
| LEADER |
01000caa a22002652c 4500 |
| 001 |
NLM368710335 |
| 003 |
DE-627 |
| 005 |
20250305201423.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
240222s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202401711
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n1228.xml
|
| 035 |
|
|
|a (DE-627)NLM368710335
|
| 035 |
|
|
|a (NLM)38381000
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Shi, Zhangqin
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Mechanically Interlocked Interphase with Energy Dissipation and Fast Li-Ion Transport for High-Capacity Lithium Metal Batteries
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 07.06.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2024 Wiley‐VCH GmbH.
|
| 520 |
|
|
|a Constructing an artificial solid electrolyte interphase (ASEI) on Li metal anodes (LMAs) is a potential strategy for addressing the dendrite issues. However, the mechanical fatigue of the ASEI caused by stress accumulation under the repeated deformation from the Li plating/stripping is not taken seriously. Herein, this work introduces a mechanically interlocked [an]daisy chain network (DCMIN) into the ASEI to stabilize the Li metal/ASEI interface by combining the functions of energy dissipation and fast Li-ion transport. The DCMIN featured by large-range molecular motions is cross-linked via efficient thiol-ene click chemistry; thus, the DCMIN has flexibility and excellent mechanical properties. As an ASEI, the crown ether units in DCMIN not only interact with the dialkylammonium of a flexible chain, forming the energy dissipation behavior but also coordinate with Li ion to support the fast Li-ion transport in DCMIN. Therefore, a stable 2800 h-symmetrical cycling (1 mA cm-2) and an excellent 5 C-rate (full cell with LiFePO4) performance are achieved by DCMIN-based ASEI. Furthermore, the 1-Ah pouch cell (LiNi0.88Co0.09Mn0.03O2 cathode) with DCMIN-coated LMA exhibits improved capacity retention (88%) relative to the Control. The molecular design of DCMIN provides new insights into the optimization of an ASEI for high-energy LMAs
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Li metal battery
|
| 650 |
|
4 |
|a energy dissipation
|
| 650 |
|
4 |
|a fast Li‐ion transport
|
| 650 |
|
4 |
|a mechanically interlocked network
|
| 650 |
|
4 |
|a solid electrolyte interphase
|
| 700 |
1 |
|
|a Wang, Yongming
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yue, Xinyang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhao, Jun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Fang, Mingming
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Jijiang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chen, Yuanmao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Dong, Yongteng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yan, Xuzhou
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liang, Zheng
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 23 vom: 01. Juni, Seite e2401711
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:23
|g day:01
|g month:06
|g pages:e2401711
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202401711
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 23
|b 01
|c 06
|h e2401711
|