|
|
|
|
| LEADER |
01000caa a22002652c 4500 |
| 001 |
NLM368657973 |
| 003 |
DE-627 |
| 005 |
20250305200700.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
240220s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202401103
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n1228.xml
|
| 035 |
|
|
|a (DE-627)NLM368657973
|
| 035 |
|
|
|a (NLM)38375740
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Li, Xinhao
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Strain Regulation of Mixed-Halide Perovskites Enables High-Performance Wide-Bandgap Photovoltaics
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 07.06.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2024 Wiley‐VCH GmbH.
|
| 520 |
|
|
|a Wide-bandgap mixed-halogen perovskite materials are widely used as top cells in tandem solar cells. However, serious open-circuit voltage (Voc) loss restricts the power conversion efficiency (PCE) of wide-bandgap perovskite solar cells (PSCs). Herein, it is shown that the resulting methylammonium vacancies induce lattice distortion in methylammonium chloride-assisted perovskite film, resulting in an inhomogeneous halogen distribution and low Voc. Thus, a lattice strain regulation strategy is reported to fabricate high-performance wide-bandgap PSCs. Rubidium (Rb) cations are introduced to fill the A-site vacancy caused by the methylammonium volatilization, which alleviates shrinkage strain of the perovskite crystal. The reduced lattice distortion and increased halide ion migration barrier result in a homogeneous mixed-halide perovskite film. Due to improved carrier transport and suppressed nonradiative recombination, the Rb-treated wide-bandgap PSC (1.68 eV) achieves an excellent PCE of 21.72%, accompanied by a high Voc of 1.22 V. The resulting device maintains more than 90% of its initial PCE after 1500 h under 1-sun illumination conditions
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a homogeneous halogen distribution
|
| 650 |
|
4 |
|a lattice strain
|
| 650 |
|
4 |
|a mixed‐halogen perovskite
|
| 650 |
|
4 |
|a open‐circuit voltage loss
|
| 650 |
|
4 |
|a wide‐bandgap photovoltaics
|
| 700 |
1 |
|
|a Li, Yifan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Feng, Yanxing
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Qi, Jiahui
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Shen, Jinliang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Shi, Guodong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Shaopeng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yuan, Mingjian
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a He, Tingwei
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 23 vom: 07. Juni, Seite e2401103
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:23
|g day:07
|g month:06
|g pages:e2401103
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202401103
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 23
|b 07
|c 06
|h e2401103
|