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240213s2023 xx |||||o 00| ||eng c |
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|a 10.1021/acs.chemmater.3c01389
|2 doi
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|a pubmed24n1291.xml
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|e rakwb
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|a eng
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|a Romero-Ángel, María
|e verfasserin
|4 aut
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|a Vapor-Assisted Conversion of Heterobimetallic Titanium-Organic Framework Thin Films
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|c 2023
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|a Text
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Revised 13.02.2024
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|a published: Electronic-eCollection
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|a Citation Status PubMed-not-MEDLINE
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|a © 2023 American Chemical Society.
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|a Heterobimetallic Metal-Organic Frameworks (MOFs) synergically combine the properties of two metal ions, thus offering significant advantages over homometallic MOFs in gas storage, separation, and catalysis, among other applications. However, these remain centered on bulk materials, while applications that require functional coatings on solid supports are not developed. We explore for the first time the deposition of heterometallic Ti-based MOF thin films using vapor-assisted conversion on substrates functionalized with a self-assembled monolayer. Furthermore, metal-induced dynamic topological transformation allows the conversion of MUV-10(Ca) films into MUV-101(Co) and MUV-102(Cu), which is not accessible through direct synthesis, without morphologically altering the films. These nonconventional thin-film deposition techniques enable homogeneous and crystalline coatings of heterometallic titanium MOFs that also maintain their corresponding porosity
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|a Journal Article
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|a Rubio-Giménez, Víctor
|e verfasserin
|4 aut
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|a Gómez-Oliveira, Eloy P
|e verfasserin
|4 aut
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|a Verstreken, Margot F K
|e verfasserin
|4 aut
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|a Smets, Jorid
|e verfasserin
|4 aut
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|a Gándara-Loe, Jesús
|e verfasserin
|4 aut
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|a M Padial, Natalia
|e verfasserin
|4 aut
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|a Ameloot, Rob
|e verfasserin
|4 aut
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|a Tatay, Sergio
|e verfasserin
|4 aut
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|a Martí-Gastaldo, Carlos
|e verfasserin
|4 aut
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|i Enthalten in
|t Chemistry of materials : a publication of the American Chemical Society
|d 1998
|g 35(2023), 24 vom: 26. Dez., Seite 10394-10402
|w (DE-627)NLM098194763
|x 0897-4756
|7 nnns
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|g volume:35
|g year:2023
|g number:24
|g day:26
|g month:12
|g pages:10394-10402
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|u http://dx.doi.org/10.1021/acs.chemmater.3c01389
|3 Volltext
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