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240131s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202312661
|2 doi
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|a pubmed24n1432.xml
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|a (NLM)38290062
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|a DE-627
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|e rakwb
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|a eng
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| 100 |
1 |
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|a Li, Jia-Xin
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Highly Stable Organic Molecular Porous Solid Electrolyte with One-Dimensional Ion Migration Channel for Solid-State Lithium-Oxygen Battery
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|c 2024
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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| 338 |
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Revised 07.06.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2024 Wiley‐VCH GmbH.
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|a Solid-state lithium-oxygen (Li-O2) batteries have been widely recognized as one of the candidates for the next-generation of energy storage batteries. However, the development of solid-state Li-O2 batteries has been hindered by the lack of solid-state electrolyte (SSE) with high ionic conductivity at room temperature, high Li+ transference number, and the high stability to air. Herein, the organic molecular porous solid cucurbit[7]uril (CB[7]) with one-dimensional (1D) ion migration channels is developed as the SSE for solid-state Li-O2 batteries. Taking advantage of the 1D ion migration channel for Li+ conduction, CB[7] SSE achieves high ionic conductivity (2.45 × 10-4 S cm-1 at 25 °C). Moreover, the noncovalent interactions facilitated the immobilization of anions, realizing a high Li+ transference number (tLi + = 0.81) and Li+ uniform distribution. The CB[7] SSE also shows a wide electrochemical stability window of 0-4.65 V and high thermal stability and chemical stability, as well as realizes stable Li+ plating/stripping (more than 1000 h at 0.3 mA cm-2). As a result, the CB[7] SSE endows solid-state Li-O2 batteries with superior rate capability and long-term discharge/charge stability (up to 500 h). This design strategy of CB[7] SSE paves the way for stable and efficient solid-state Li-O2 batteries toward practical applications
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|a Journal Article
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|a Li–O2 batteries
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| 650 |
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4 |
|a electrochemical performance
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| 650 |
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|a organic molecular porous solid
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| 650 |
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4 |
|a solid‐state electrolytes
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| 700 |
1 |
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|a Guan, De-Hui
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wang, Xiao-Xue
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Miao, Cheng-Lin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Li, Jian-You
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Xu, Ji-Jing
|e verfasserin
|4 aut
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| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 23 vom: 07. Juni, Seite e2312661
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
1 |
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|g volume:36
|g year:2024
|g number:23
|g day:07
|g month:06
|g pages:e2312661
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| 856 |
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|u http://dx.doi.org/10.1002/adma.202312661
|3 Volltext
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