Atomic-Scale Visualization of Multiferroicity in Monolayer NiI2

© 2024 The Authors. Advanced Materials published by Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 36(2024), 18 vom: 01. Mai, Seite e2311342
1. Verfasser: Amini, Mohammad (VerfasserIn)
Weitere Verfasser: Fumega, Adolfo O, González-Herrero, Héctor, Vaňo, Viliam, Kezilebieke, Shawulienu, Lado, Jose L, Liljeroth, Peter
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article density‐functional theory calculations magneto electric coupling multiferroic order scanning tunneling microscopy two‐dimensional multiferroics
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520 |a Progress in layered van der Waals materials has resulted in the discovery of ferromagnetic and ferroelectric materials down to the monolayer limit. Recently, evidence of the first purely 2D multiferroic material was reported in monolayer NiI2. However, probing multiferroicity with scattering-based and optical bulk techniques is challenging on 2D materials, and experiments on the atomic scale are needed to fully characterize the multiferroic order at the monolayer limit. Here, scanning tunneling microscopy (STM) supported by density functional theory (DFT) calculations is used to probe and characterize the multiferroic order in monolayer NiI2. It is demonstrated that the type-II multiferroic order displayed by NiI2, arising from the combination of a magnetic spin spiral order and a strong spin-orbit coupling, allows probing the multiferroic order in the STM experiments. Moreover, the magnetoelectric coupling of NiI2 is directly probed by external electric field manipulation of the multiferroic domains. The findings establish a novel point of view to analyze magnetoelectric effects at the microscopic level, paving the way toward engineering new multiferroic orders in van der Waals materials and their heterostructures 
650 4 |a Journal Article 
650 4 |a density‐functional theory calculations 
650 4 |a magneto electric coupling 
650 4 |a multiferroic order 
650 4 |a scanning tunneling microscopy 
650 4 |a two‐dimensional multiferroics 
700 1 |a Fumega, Adolfo O  |e verfasserin  |4 aut 
700 1 |a González-Herrero, Héctor  |e verfasserin  |4 aut 
700 1 |a Vaňo, Viliam  |e verfasserin  |4 aut 
700 1 |a Kezilebieke, Shawulienu  |e verfasserin  |4 aut 
700 1 |a Lado, Jose L  |e verfasserin  |4 aut 
700 1 |a Liljeroth, Peter  |e verfasserin  |4 aut 
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773 1 8 |g volume:36  |g year:2024  |g number:18  |g day:01  |g month:05  |g pages:e2311342 
856 4 0 |u http://dx.doi.org/10.1002/adma.202311342  |3 Volltext 
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