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240118s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202310356
|2 doi
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|a pubmed25n1223.xml
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|a (DE-627)NLM36723257X
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|a (NLM)38232743
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|a DE-627
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|a eng
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|a Xu, Shijie
|e verfasserin
|4 aut
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|a Performance Enhancement of the Li6PS5Cl-Based Solid-State Batteries by Scavenging Lithium Dendrites with LaCl3-Based Electrolyte
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|c 2024
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 11.04.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2024 Wiley‐VCH GmbH.
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|a Li6PS5Cl (LPSC) is a very attractive sulfide solid electrolyte for developing high-performance all-solid-state lithium batteries. However, it cannot suppress the growth of lithium dendrites and then can only tolerate a small critical current density (CCD) before getting short-circuited to death. Learning from that a newly-developed LaCl3-based electrolyte (LTLC) can afford a very large CCD, a three-layer sandwich-structured electrolyte is designed by inserting LTLC inside LPSC. Remarkably, compared with bland LPSC, this hybrid electrolyte LPSC/LTLC/LPSC presents extraordinary performance improvements: the CCD gets increased from 0.51 to 1.52 mA cm-2, the lifetime gets prolonged from 7 h to >500 h at the cycling current of 0.5 mA cm-2 in symmetric cells, and the cyclability gets extended from 10 cycles to >200 cycles at the cycling rate of 0.5 C and 30 °C in Li|electrolyte|NCM721 full cells. The enhancing reasons are assigned to the capability of LTLC to scavenge lithium dendrites, forming a passive layer of Ta, La, and LiCl
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|a Journal Article
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|a all‐solid‐state lithium batteries
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|a lithium dendrites
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|a lithium lanthanum tantalum chloride
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|a lithium phosphorus sulfur chloride
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|a sulfide solid electrolytes
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|a Cheng, Xiaobin
|e verfasserin
|4 aut
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|a Yang, Shunjin
|e verfasserin
|4 aut
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| 700 |
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|a Yin, Yichen
|e verfasserin
|4 aut
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|a Wang, Xinyu
|e verfasserin
|4 aut
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1 |
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|a Zhang, Yuzhe
|e verfasserin
|4 aut
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|a Ren, Dehang
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Sun, Yujiang
|e verfasserin
|4 aut
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| 700 |
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|a Sun, Xiao
|e verfasserin
|4 aut
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|a Yao, Hongbin
|e verfasserin
|4 aut
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| 700 |
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|a Yang, Yongan
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 15 vom: 22. Apr., Seite e2310356
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
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| 773 |
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|g volume:36
|g year:2024
|g number:15
|g day:22
|g month:04
|g pages:e2310356
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|u http://dx.doi.org/10.1002/adma.202310356
|3 Volltext
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