High-Entropy Alloy PtCuNiCoMn Nanoparticles on rGO for Electrooxidation of Methanol and Formic Acid

High-entropy alloy (HEA) nanoparticles have attracted great attention due to their excellent electrocatalytic properties. Herein, PtCuNiCoMn HEA nanoparticles supported on reduced graphene oxide (rGO) are synthesized via a solvothermal co-reduction method and are used as an electrocatalyst for the e...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1999. - 40(2024), 4 vom: 30. Jan., Seite 2343-2351
1. Verfasser: Cheng, Wenting (VerfasserIn)
Weitere Verfasser: Sun, Chengrui, Liu, Wen, Wang, Zhenghua
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a High-entropy alloy (HEA) nanoparticles have attracted great attention due to their excellent electrocatalytic properties. Herein, PtCuNiCoMn HEA nanoparticles supported on reduced graphene oxide (rGO) are synthesized via a solvothermal co-reduction method and are used as an electrocatalyst for the electrooxidation of methanol and formic acid. Owing to the synergistic effect between the component metals, the high-entropy effect, and the sluggish diffusion effect, the PtCuNiCoMn HEA nanoparticles possess significantly improved electrocatalytic activity and stability compared to PtCuNiCo, PtCuNi, PtCu, Pt nanoparticles, and the commercial Pt/C catalyst. The results reveal the unique advantages of HEA nanoparticles in the field of electrocatalysis. The synthesis method is simple and effective, which may be valuable for the preparation of other HEA electrocatalysts 
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