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240108s2024 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.3c03164
|2 doi
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|a pubmed24n1268.xml
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|a (NLM)38180481
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Tao, Yahui
|e verfasserin
|4 aut
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|a Swallowed Embedding of Nanopetal-Rich Microflowers in Flexible Photocatalytic and Thermoresponsive Functional Composite Fibers
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|c 2024
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 23.01.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Developing efficient catalysts to degrade pollutants in water is a very important way to alleviate water pollution. However, it is crucial but challenging to broaden the functions of conventional photocatalysts and improve their environmental adaptability. In this paper, Bi(Er3+/Yb3+)OBr/polyacrylonitrile (BOB-EY/PAN) composite fibers with a swallowed-embedded structure assembled with nanopetal-rich microflowers were designed and fabricated, integrating photocatalytic and temperature-monitoring functions simultaneously. Their unique structure brings a large specific surface area, and the doping of rare earth ions improves the separation efficiency of electron-hole pairs, which enhances the photocatalytic efficiency and endows the fibers with a temperature-monitoring function at the same time. Under simulated sunlight irradiation, the nanofibers show a maximum degradation efficiency of 99.2% for tetracycline hydrochloride (TC) with a degradation constant of K as high as 0.078 min-1. Based on the fluorescence intensity ratio (FIR), the two thermally coupled levels of Er3+ in the nanofibers, 2H11/2 and 4S3/2, provide real-time temperature feedback, displaying a maximum relative sensitivity as high as 0.0215 K-1 at 303 K. Dual-functional BOB-EY/PAN composite nanofibers show great potential for industrial wastewater disposition, providing solutions for wastewater purification in special scenarios
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|a Journal Article
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|a Luo, Qian
|e verfasserin
|4 aut
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|a Shen, Lifan
|e verfasserin
|4 aut
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|a Hong, Feng
|e verfasserin
|4 aut
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|a Pun, Edwin Yue Bun
|e verfasserin
|4 aut
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|a Lin, Hai
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 40(2024), 3 vom: 23. Jan., Seite 1825-1839
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:40
|g year:2024
|g number:3
|g day:23
|g month:01
|g pages:1825-1839
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|u http://dx.doi.org/10.1021/acs.langmuir.3c03164
|3 Volltext
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