|
|
|
|
| LEADER |
01000caa a22002652c 4500 |
| 001 |
NLM365418463 |
| 003 |
DE-627 |
| 005 |
20250305125346.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202308590
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n1217.xml
|
| 035 |
|
|
|a (DE-627)NLM365418463
|
| 035 |
|
|
|a (NLM)38050893
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Zhao, Mingcai
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Unveiling Challenges and Opportunities in Silicon-Based All-Solid-State Batteries
|b Thin-Film Bonding with Mismatch Strain
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 25.01.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2023 Wiley-VCH GmbH.
|
| 520 |
|
|
|a Li-metal and silicon are potential anode materials in all-solid-state Li-ion batteries (ASSBs) due to high specific capacity. However, both materials form gaps at the interface with solid electrolytes (SEs) during charging/discharging, resulting in increased impedance and uneven current density distribution. In this perspective, the different mechanisms of formation of these gaps are elaborated in detail. For Li-metal anodes, Li-ions are repeatedly stripped and unevenly deposited on the surface, leading to gaps and Li dendrite formation, which is an unavoidable electrochemical behavior. For Si-based anodes, Li-ions inserting/extracting within the Si-based electrode causes volume changes and a local separation from the SE, which is a mechanical behavior and avoidable by mitigating the strain mismatch of thin-film bonding between anode and SE. Si electro-chemical-mechanical behaviors are also described and strategies recommended to synergistically decrease Si-based electrode strain, including Si materials, Si-based composites, and electrodes. Last, it is suggested to choose a composite polymer-inorganic SE with favorable elastic properties and high ionic conductivity and form it directly on the Si-based electrode, beneficial for increasing SE strain to accommodate stack pressure and the stability of the interface. Thus, this perspective sheds light on the development and application of Si-based ASSBs
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a composite polymer-inorganic electrolytes
|
| 650 |
|
4 |
|a electro-chemical-mechanical behaviors
|
| 650 |
|
4 |
|a irreversible expansion
|
| 650 |
|
4 |
|a mismatch strain
|
| 650 |
|
4 |
|a Si-based all-solid-state battery
|
| 700 |
1 |
|
|a Zhang, Juan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Costa, Carlos M
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lanceros-Méndez, Senentxu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Qi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Wei
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 4 vom: 04. Jan., Seite e2308590
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:4
|g day:04
|g month:01
|g pages:e2308590
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202308590
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 4
|b 04
|c 01
|h e2308590
|