Porous organic semiconductor/PET composite fibre for the synergistic removal of hexavalent chromium and organic pollutants under sunlight

In this study, the porous graphite phase carbon nitride photocatalyst (P-g-C3N4) is prepared by the CaCO3 template method, and then P-g-C3N4/T-polyethylene terephthalate (T-PET) catalytic fibre is prepared by the padding method. P-g-C3N4 can provide more active sites than g-C3N4 as proved by the Bru...

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Veröffentlicht in:Environmental technology. - 1993. - 45(2024), 23 vom: 06. Sept., Seite 4766-4778
1. Verfasser: Shen, Zhenyu (VerfasserIn)
Weitere Verfasser: Zhu, Zhexin, Wang, Gangqiang, Miao, Yongquan, Lu, Wangyang
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article P-g-C3N4/T-PET Photocatalytic degradation hexavalent chromium organic pollutants Chromium 0R0008Q3JB chromium hexavalent ion 18540-29-9 Water Pollutants, Chemical mehr... Polyethylene Terephthalates Nitriles Graphite 7782-42-5
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520 |a In this study, the porous graphite phase carbon nitride photocatalyst (P-g-C3N4) is prepared by the CaCO3 template method, and then P-g-C3N4/T-polyethylene terephthalate (T-PET) catalytic fibre is prepared by the padding method. P-g-C3N4 can provide more active sites than g-C3N4 as proved by the Brunauer-Emmett-Teller and the UV-Visible diffuse reflectance test. P-g-C3N4 powder catalyst successfully supports PET fibre as proved by scanning electron microscope, Fourier infrared spectroscopy and X-ray diffraction spectroscopy. The photocatalytic performance of P-g-C3N4/T-PET catalytic fibre is tested by constructing a single hexavalent chromium or hexavalent chromium/organic pollutant binary pollution system. The potential application value of P-g-C3N4/T-PET catalytic fibre is further explored by simulating the complex actual water environment. After five recycles, P-g-C3N4/T-PET catalytic fibre shows good catalytic performance. The mechanism of P-g-C3N4/PET photocatalytic degradation of organic pollutants is proposed through the capture agent experiment and electron paramagnetic resonance spectroscopy. Among them, •O2- is the most important active species of P-g-C3N4 catalytic fibre, which is used for the oxidation of organic pollutants. At the same time, photoelectrons generated by the catalytic fibre are used to reduce hexavalent chromium. The efficiency of P-g-C3N4 to remove pollutants is improved by using PET fibre as a carrier, which not only solves the problem of difficult recovery of powder catalysts but also provides more active sites 
650 4 |a Journal Article 
650 4 |a P-g-C3N4/T-PET 
650 4 |a Photocatalytic degradation 
650 4 |a hexavalent chromium 
650 4 |a organic pollutants 
650 7 |a Chromium  |2 NLM 
650 7 |a 0R0008Q3JB  |2 NLM 
650 7 |a chromium hexavalent ion  |2 NLM 
650 7 |a 18540-29-9  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a Polyethylene Terephthalates  |2 NLM 
650 7 |a Nitriles  |2 NLM 
650 7 |a Graphite  |2 NLM 
650 7 |a 7782-42-5  |2 NLM 
700 1 |a Zhu, Zhexin  |e verfasserin  |4 aut 
700 1 |a Wang, Gangqiang  |e verfasserin  |4 aut 
700 1 |a Miao, Yongquan  |e verfasserin  |4 aut 
700 1 |a Lu, Wangyang  |e verfasserin  |4 aut 
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773 1 8 |g volume:45  |g year:2024  |g number:23  |g day:06  |g month:09  |g pages:4766-4778 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2023.2283085  |3 Volltext 
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