An entire recycling of spent Al-bearing cathode powder as giniite sphere and lithiophophate plate with leaching-hydrothermal-precipitation process

Spent lithium battery is a polymetallic waste, and valuable to be recovered as Li-bearing chemical with the barriers of impurities separation, especially Fe and Al. Here in, Li-rich cathode powder was manually disassembled from spent battery, and then recovered as lithiophosphate plate in considerat...

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Veröffentlicht in:Environmental technology. - 1993. - 45(2024), 24 vom: 01. Sept., Seite 5037-5047
1. Verfasser: Pan, Jingyi (VerfasserIn)
Weitere Verfasser: Su, Ting, Chen, Hongyu, Bian, Rui, Gao, Chengjie, Ruan, Zhuowei, Zhu, Suiyi
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Spent lithium battery cathode powder hydrothermal treatment lithiophosphate recycling Aluminum CPD4NFA903 Lithium 9FN79X2M3F Powders
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520 |a Spent lithium battery is a polymetallic waste, and valuable to be recovered as Li-bearing chemical with the barriers of impurities separation, especially Fe and Al. Here in, Li-rich cathode powder was manually disassembled from spent battery, and then recovered as lithiophosphate plate in consideration of effective separation of impure Fe/Al. The powder comprised of 23.2% Fe, 3.2% Al, 5.5% Li and 19.6% P, and then dissolved by azotic acid as Li-rich solution. When the solution was heated to 190°C for 10 h with the supplementary of saccharose, more than 99.9% Fe and 98.9% Al were removed as spherical giniite particles, in accordance with the rest of Fe/Al at the concentrations of 2.1 and 14 mg/L, whilst the loss of Li was less than 1.5%. But without saccharose, the Fe/Al removals only achieved by 99.2% and 52.1%. It is also found that the Fe/Al/Li removal achieved by 99.6%, 96% and 25.3% after adjusting the solution to pH 2.7 by NaOH. After hydrothermal treatment, the rest Li can be recycled as lithiophosphate plate by pH adjustment, in contrast to the recovery efficiency of 98.5% Li. Such method raised a facile route to effectively separate impure Fe/Al from Li-rich cathode powder, and showed promising application in the industrial recovery of spent battery 
650 4 |a Journal Article 
650 4 |a Spent lithium battery 
650 4 |a cathode powder 
650 4 |a hydrothermal treatment 
650 4 |a lithiophosphate 
650 4 |a recycling 
650 7 |a Aluminum  |2 NLM 
650 7 |a CPD4NFA903  |2 NLM 
650 7 |a Lithium  |2 NLM 
650 7 |a 9FN79X2M3F  |2 NLM 
650 7 |a Powders  |2 NLM 
700 1 |a Su, Ting  |e verfasserin  |4 aut 
700 1 |a Chen, Hongyu  |e verfasserin  |4 aut 
700 1 |a Bian, Rui  |e verfasserin  |4 aut 
700 1 |a Gao, Chengjie  |e verfasserin  |4 aut 
700 1 |a Ruan, Zhuowei  |e verfasserin  |4 aut 
700 1 |a Zhu, Suiyi  |e verfasserin  |4 aut 
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773 1 8 |g volume:45  |g year:2024  |g number:24  |g day:01  |g month:09  |g pages:5037-5047 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2023.2283796  |3 Volltext 
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