|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM364623381 |
| 003 |
DE-627 |
| 005 |
20231226095822.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2023 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.langmuir.3c02123
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1215.xml
|
| 035 |
|
|
|a (DE-627)NLM364623381
|
| 035 |
|
|
|a (NLM)37970757
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Bou Tannous, Layla
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Effect of Surface Chemistry on the Electrical Double Layer in a Long-Chain Ionic Liquid
|
| 264 |
|
1 |
|c 2023
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 28.11.2023
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a Room temperature ionic liquids (ILs) can create a strong accumulation of charges at solid interfaces by forming a very thin and dense electrical double layer (EDL). The structure of this EDL has important consequences in numerous applications involving ILs, for example, in supercapacitors, sensors, and lubricants, by impacting the interfacial capacitance, the charge carrier density of semiconductors, as well as the frictional properties of the interfaces. We have studied the interfacial structure of a long chain imidazolium-based IL (1-octyl-3-methylimidazolium dicyanamide) on several substrates: mica, silica, silicon, and molybdenum disulfide (MoS2), using atomic force microscopy (AFM) experiments and molecular dynamics (MD) simulations. We have observed 3 types of interfacial structures for the same IL, depending on the chemistry of the substrate and the water content, showing that the EDL structure is not an intrinsic property of the IL. We evidenced that at a low water content, neutral and apolar (thus hydrophobic) substrates promote a thin layer structure, where the ions are oriented parallel to the substrate and cations and anions are mixed in each layer. In contrast, a strongly charged (thus hydrophilic) substrate yields an extended structuration into several bilayers, while a heterogeneous layering with loose bilayer regions was observed on an intermediate polar and weakly charged substrate and on an apolar one at a high bulk water content. In the latter case, water contamination favors the formation of bilayer patches by promoting the segregation of the long chain IL into polar and apolar domains
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Simoes Santos, Mirella
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Gong, Zheng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Haumesser, Paul-Henri
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Benayad, Anass
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Padua, Agilio A H
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Steinberger, Audrey
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 39(2023), 47 vom: 28. Nov., Seite 16785-16796
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:39
|g year:2023
|g number:47
|g day:28
|g month:11
|g pages:16785-16796
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.langmuir.3c02123
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 39
|j 2023
|e 47
|b 28
|c 11
|h 16785-16796
|