Polymerization of Physisorbed Molecular Monolayers via Overhanging Alkynyl Chains : Characterization of Polymerization Kinetics and Monolayer Durability

Monolayers self-assembled by triphenyleneethynylene (TPE) compounds bearing two terminal alkynyl chains were polymerized by Glaser-Hay (G-H) alkyne coupling at the acetonitrile-HOPG interface. The alkynyl chains extend into the solution due to the monolayer's dense-packed morphology. Reacting s...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1999. - 39(2023), 46 vom: 21. Nov., Seite 16457-16471
1. Verfasser: Wilczek, Luke A (VerfasserIn)
Weitere Verfasser: Geiser, Joseph D, Fang, Chen, Hicks, Emily G, Dube, Lacie, Hipps, K W, Zimmt, Matthew B
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article