|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM363951989 |
| 003 |
DE-627 |
| 005 |
20240118231935.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202306145
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1263.xml
|
| 035 |
|
|
|a (DE-627)NLM363951989
|
| 035 |
|
|
|a (NLM)37903216
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Wang, Chenxiang
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Labile Coordination Interphase for Regulating Lean Ion Dynamics in Reversible Zn Batteries
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 18.01.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2023 Wiley-VCH GmbH.
|
| 520 |
|
|
|a Rechargeability in zinc (Zn) batteries is limited by anode irreversibility. The practical lean electrolytes exacerbate the issue, compromising the cost benefits of zinc batteries for large-scale energy storage. In this study, a zinc-coordinated interphase is developed to avoid chemical corrosion and stabilize zinc anodes. The interphase promotes Zn2+ ions to selectively bind with histidine and carboxylate ligands, creating a coordination environment with high affinity and fast diffusion due to thermodynamic stability and kinetic lability. Experiments and simulations indicate that interphase regulates dendrite-free electrodeposition and reduces side reactions. Implementing such labile coordination interphase results in increased cycling at 20 mA cm-2 and high reversibility of dendrite-free zinc plating/stripping for over 200 hours. A Zn||LiMn2 O4 cell with 74.7 mWh g-1 energy density and 99.7% Coulombic efficiency after 500 cycles realized enhanced reversibility using the labile coordination interphase. A lean-electrolyte full cell using only 10 µL mAh-1 electrolyte is also demonstrated with an elongated lifespan of 100 cycles, five times longer than bare Zn anodes. The cell offers a higher energy density than most existing aqueous batteries. This study presents a proof-of-concept design for low-electrolyte, high-energy-density batteries by modulating coordination interphases on Zn anodes
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a artificial interphase layer
|
| 650 |
|
4 |
|a labile and stable coordination
|
| 650 |
|
4 |
|a lean electrolyte batteries
|
| 650 |
|
4 |
|a reversible cycling
|
| 650 |
|
4 |
|a zinc anodes
|
| 700 |
1 |
|
|a Zhu, Jason Zi Jie
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Vi-Tang, Samantha
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Peng, Bosi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ni, Chenhao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Qizhou
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chang, Xueying
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Huang, Ailun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Zhiyin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Savage, Ethan J
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Uemura, Sophia
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Katsuyama, Yuto
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a El-Kady, Maher F
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Kaner, Richard B
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 3 vom: 06. Jan., Seite e2306145
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:3
|g day:06
|g month:01
|g pages:e2306145
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202306145
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 3
|b 06
|c 01
|h e2306145
|