|
|
|
|
| LEADER |
01000caa a22002652c 4500 |
| 001 |
NLM363786937 |
| 003 |
DE-627 |
| 005 |
20250305093015.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2023 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.organomet.3c00339
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n1212.xml
|
| 035 |
|
|
|a (DE-627)NLM363786937
|
| 035 |
|
|
|a (NLM)37886624
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Farcaş-Johnson, Mirela A
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Iron(II)-Catalyzed Activation of Si-N and Si-O Bonds Using Hydroboranes
|
| 264 |
|
1 |
|c 2023
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 28.10.2023
|
| 500 |
|
|
|a published: Electronic-eCollection
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2023 The Authors. Published by American Chemical Society.
|
| 520 |
|
|
|a We report the activation and functionalization of Si-N bonds with pinacol borane catalyzed by a three-coordinate iron(II) β-diketiminate complex. The reactions proceed via the mild activation of silazanes to yield useful hydrosilanes and aminoboranes. The reaction is studied by kinetic analysis, along with a detailed investigation of decomposition pathways using catecholborane as an analogue of the pinacol borane used in catalysis. We have extended the methodology to develop a polycarbosilazane depolymerization strategy, which generates hydrosilane quantitatively along with complete conversion to the Bpin-protected diamine. The analogous Si-O bond cleavage can also be achieved with heating, using silyl ether starting materials to generate hydrosilane and alkoxyborane products. Depolymerization of poly(silyl ether)s using our strategy successfully converts the polymer to 90% Bpin-protected alcohols
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Gasperini, Danila
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a King, Andrew K
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Mohan, Sakshi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Barrett, Adam N
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lau, Samantha
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Mahon, Mary F
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Sarazin, Yann
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Kyne, Sara H
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Webster, Ruth L
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Organometallics
|d 1998
|g 42(2023), 20 vom: 23. Okt., Seite 3013-3024
|w (DE-627)NLM098167103
|x 0276-7333
|7 nnas
|
| 773 |
1 |
8 |
|g volume:42
|g year:2023
|g number:20
|g day:23
|g month:10
|g pages:3013-3024
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.organomet.3c00339
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 42
|j 2023
|e 20
|b 23
|c 10
|h 3013-3024
|