Low-Cost Hydrogen Production from Alkaline/Seawater over a Single-Step Synthesis of Mo3 Se4 -NiSe Core-Shell Nanowire Arrays
© 2023 Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 36(2024), 5 vom: 19. Feb., Seite e2305813 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2024
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article Mo3Se4-NiSe core-shell density functional theory calculations hydrogen evolution reaction natural seawater electrolysis one-pot synthesis |
| Zusammenfassung: | © 2023 Wiley-VCH GmbH. The rational design and steering of earth-abundant, efficient, and stable electrocatalysts for hydrogen generation is highly desirable but challenging with catalysts free of platinum group metals (PGMs). Mass production of high-purity hydrogen fuel from seawater electrolysis presents a transformative technology for sustainable alternatives. Here, a heterostructure of molybdenum selenide-nickel selenide (Mo3 Se4 -NiSe) core-shell nanowire arrays constructed on nickel foam by a single-step in situ hydrothermal process is reported. This tiered structure provides improved intrinsic activity and high electrical conductivity for efficient charge transfer and endows excellent hydrogen evolution reaction (HER) activity in alkaline and natural seawater conditions. The Mo3 Se4 -NiSe freestanding electrodes require small overpotentials of 84.4 and 166 mV to reach a current density of 10 mA cm-2 in alkaline and natural seawater electrolytes, respectively. It maintains an impressive balance between electrocatalytic activity and stability. Experimental and theoretical calculations reveal that the Mo3 Se4 -NiSe interface provides abundant active sites for the HER process, which modulate the binding energies of adsorbed species and decrease the energetic barrier, providing a new route to design state-of-the-art, PGM-free catalysts for hydrogen production from alkaline and seawater electrolysis |
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| Beschreibung: | Date Revised 01.02.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202305813 |