Stability and Structural Analysis Using Small-Angle Neutron Scattering for Foam of Homogeneous Polyoxyethylene-Type Nonionic Surfactants with Multibranched Chains

Small-angle neutron scattering can provide insight into the microstructure of the surfactant-stabilized foam. In this study, small-angle neutron scattering in combination with other techniques was employed to determine the microstructure of the foams stabilized using novel homogeneous polyoxyethylen...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1999. - 39(2023), 43 vom: 31. Okt., Seite 15355-15361
1. Verfasser: Yada, Shiho (VerfasserIn)
Weitere Verfasser: Kuroda, Mizuho, Ohno, Masashi, Koda, Toshinari, Yoshimura, Tomokazu
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Stability and Structural Analysis Using Small-Angle Neutron Scattering for Foam of Homogeneous Polyoxyethylene-Type Nonionic Surfactants with Multibranched Chains 
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520 |a Small-angle neutron scattering can provide insight into the microstructure of the surfactant-stabilized foam. In this study, small-angle neutron scattering in combination with other techniques was employed to determine the microstructure of the foams stabilized using novel homogeneous polyoxyethylene (EO) alkyl ether-type nonionic surfactants with multibranched double chains (bC7-bC9EO12). Similarly, homogeneous EO-type nonionic surfactants with linear double chains (C8-C8EO12) and a linear single chain (C18EO12) were used. bC7-bC9EO12 and C8-C8EO12 surfactants with branched hydrophobic chains or double chains increased the foam stability and suppressed the draining. Furthermore, they formed rod-like micelles, and C18EO12 formed spherical micelles in the bulk solution. The foam film containing the plateau border contained micelles identical with those found in the bulk solution. For bC7-bC9EO12 and C8-C8EO12, the average radius of the bubbles immediately after foaming was of the order of hundreds of μm. Finally, these radii grew to the order of thousands of μm. Thus, a significant correlation was observed between the micellar structure and the stability of these foams 
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700 1 |a Kuroda, Mizuho  |e verfasserin  |4 aut 
700 1 |a Ohno, Masashi  |e verfasserin  |4 aut 
700 1 |a Koda, Toshinari  |e verfasserin  |4 aut 
700 1 |a Yoshimura, Tomokazu  |e verfasserin  |4 aut 
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