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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.3c02424
|2 doi
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|a pubmed24n1211.xml
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|a (DE-627)NLM363370994
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|a (NLM)37844330
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Yada, Shiho
|e verfasserin
|4 aut
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|a Stability and Structural Analysis Using Small-Angle Neutron Scattering for Foam of Homogeneous Polyoxyethylene-Type Nonionic Surfactants with Multibranched Chains
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 31.10.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Small-angle neutron scattering can provide insight into the microstructure of the surfactant-stabilized foam. In this study, small-angle neutron scattering in combination with other techniques was employed to determine the microstructure of the foams stabilized using novel homogeneous polyoxyethylene (EO) alkyl ether-type nonionic surfactants with multibranched double chains (bC7-bC9EO12). Similarly, homogeneous EO-type nonionic surfactants with linear double chains (C8-C8EO12) and a linear single chain (C18EO12) were used. bC7-bC9EO12 and C8-C8EO12 surfactants with branched hydrophobic chains or double chains increased the foam stability and suppressed the draining. Furthermore, they formed rod-like micelles, and C18EO12 formed spherical micelles in the bulk solution. The foam film containing the plateau border contained micelles identical with those found in the bulk solution. For bC7-bC9EO12 and C8-C8EO12, the average radius of the bubbles immediately after foaming was of the order of hundreds of μm. Finally, these radii grew to the order of thousands of μm. Thus, a significant correlation was observed between the micellar structure and the stability of these foams
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|a Journal Article
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|a Kuroda, Mizuho
|e verfasserin
|4 aut
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|a Ohno, Masashi
|e verfasserin
|4 aut
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|a Koda, Toshinari
|e verfasserin
|4 aut
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|a Yoshimura, Tomokazu
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 39(2023), 43 vom: 31. Okt., Seite 15355-15361
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:39
|g year:2023
|g number:43
|g day:31
|g month:10
|g pages:15355-15361
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|u http://dx.doi.org/10.1021/acs.langmuir.3c02424
|3 Volltext
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|d 39
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