Investigation of the Mechanisms of CO2/O2 Adsorption Selectivity on Carbon Materials Enhanced by Oxygen Functional Groups
Power plant flue gas and industrial waste gas are produced in large quantities. Using these as feedstocks for CO2 electroreduction has important practical significance for the treatment of excessive CO2 emissions. However, O2 in such sources strongly inhibits the electrochemical conversion of CO2. T...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 39(2023), 41 vom: 17. Okt., Seite 14699-14710 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2023
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | Power plant flue gas and industrial waste gas are produced in large quantities. Using these as feedstocks for CO2 electroreduction has important practical significance for the treatment of excessive CO2 emissions. However, O2 in such sources strongly inhibits the electrochemical conversion of CO2. The inhibitory effect of O2 can be mitigated by constructing CO2-enriched regions on the surface of the cathode. In this study, the reaction zone was controlled by the selective adsorption of CO2 on oxygen-functionalized carbon materials. The results of quantum chemical simulations showed that CO2 adsorption was mainly influenced by electrostatic interactions, whereas O2 adsorption was completely regulated by dispersion interactions. This distinction indicated that introducing polar oxygen functional groups at the edge of the carbon plane can significantly enhance the selectivity for CO2/O2 adsorption. The difference in the adsorption energy between CO2 and O2 increased most noticeably after the carboxyl groups were introduced. The results of the adsorption experiments showed that oxygen-functionalization increased the CO2/O2 selectivity of the carbon material under an atmosphere of multicomponent gases by more than 4.9 times. The carboxyl groups played a dominant role. Our findings might act as a reference for the selective adsorption of polar molecules over nonpolar molecules |
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| Beschreibung: | Date Revised 31.10.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.3c02076 |