Layered Inorganic Silicate Aerogel Pillared by Nanoclusters for High Temperature Thermal Insulation

Layered Inorganic Silicate Aerogel Pillared by Nanoclusters for High Temperature Thermal Insulation

© 2023 Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 49 vom: 07. Dez., Seite e2306135
1. Verfasser: Zhou, Tianpei (VerfasserIn)
Weitere Verfasser: Xu, Yetao, Zhen, Yu, Wu, Kaijin, Ding, Honghe, Wang, Linjun, Tai, Xiaolin, Cai, Xueru, Zhang, Xun, Xia, Tianpu, Zhu, Junfa, Chu, Wangsheng, Ni, Yong, Xie, Yi, Wu, Changzheng
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article high temperature thermal insulation layered inorganic aerogel pillar effect
Beschreibung
Zusammenfassung:© 2023 Wiley-VCH GmbH.
Layered inorganic material, with large-area interlayer surface and interface, provides an essential material platform for constructing new configuration of functional materials. Herein, a layered material pillared with nanoclusters realizing high temperature thermal insulation performance is demonstrated for the first time. Specifically, systematic synchrotron radiation spectroscopy and finite element calculation analysis show that ZrOx nanoclusters served as "pillars" to effectively produce porous structures with enough boundary defect while maintaining the layered structure, thereby significantly reducing solid state thermal conductivity (≈0.32 W m-1  K-1 , 298-573 K). Moreover, the layered inorganic silicate material assembled aerogel also exhibits superior thermal insulation performance from room temperature (0.034 W m-1  K-1 , 298 K, air conditions) to high temperature (0.187 W m-1  K-1 , 1073 K, air conditions) and largely enhanced compressive strength (42 kPa at 80% compression), which is the best layered material-based aerogel that has achieved synergistic improvement in thermal and mechanical performance so far. Layered inorganic silicate aerogel pillared by nanoclusters will pave a new avenue for the design of advanced thermal insulation materials under extreme conditions
Beschreibung:Date Revised 08.12.2023
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.202306135