A Functional Janus Ag Nanowires/Bacterial Cellulose Separator for High-Performance Dendrite-Free Zinc Anode Under Harsh Conditions

© 2023 Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 47 vom: 30. Nov., Seite e2304667
1. Verfasser: Zheng, Ziyan (VerfasserIn)
Weitere Verfasser: Guo, Shaojie, Yan, Mengyu, Luo, Yanzhu, Cao, Feifei
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article Janus Ag nanowires/bacterial cellulose separators aqueous zinc batteries dendrite-free anodes high current density high temperatures
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520 |a Aqueous zinc-ion batteries (AZIBs) offer promising prospects for large-scale energy storage due to their inherent abundance and safety features. However, the growth of zinc dendrites remains a primary obstacle to the practical industrialization of AZIBs, especially under harsh conditions of high current densities and elevated temperatures. To address this issue, a Janus separator with an exceptionally ultrathin thickness of 29 µm is developed. This Janus separator features the bacterial cellulose (BC) layer on one side and Ag nanowires/bacterial cellulose (AgNWs/BC) layer on the other side. High zincophilic property and excellent electric/thermal conductivity of AgNWs make them ideal for serving as an ion pump to accelerate Zn2+ transport in the electrolyte, resulting in greatly improved Zn2+ conductivity, deposition of homogeneous Zn nuclei, and dendrite-free Zn. Consequently, the Zn||Zn symmetrical cells with the Janus separator exhibit a stable cycle life of over 1000 h under 80 mA cm-2 and are sustained for over 600 h at 10 mA cm-2 under 50 °C. Further, the Janus separator enables excellent cycling stability in AZIBs, aqueous zinc-ion capacitors (AZICs), and scaled-up flexible soft-packaged batteries. This study demonstrates the potential of functional separators in promoting the application of aqueous zinc batteries, particularly under harsh conditions 
650 4 |a Journal Article 
650 4 |a Janus Ag nanowires/bacterial cellulose separators 
650 4 |a aqueous zinc batteries 
650 4 |a dendrite-free anodes 
650 4 |a high current density 
650 4 |a high temperatures 
700 1 |a Guo, Shaojie  |e verfasserin  |4 aut 
700 1 |a Yan, Mengyu  |e verfasserin  |4 aut 
700 1 |a Luo, Yanzhu  |e verfasserin  |4 aut 
700 1 |a Cao, Feifei  |e verfasserin  |4 aut 
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773 1 8 |g volume:35  |g year:2023  |g number:47  |g day:30  |g month:11  |g pages:e2304667 
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