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231226s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202307370
|2 doi
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|a pubmed24n1248.xml
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|a eng
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|a Cheng, Xin-Bing
|e verfasserin
|4 aut
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|a Electrochemically and Thermally Stable Inorganics-Rich Solid Electrolyte Interphase for Robust Lithium Metal Batteries
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|c 2024
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Revised 04.01.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2023 Wiley-VCH GmbH.
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|a Severe dendrite growth and high-level activity of the lithium metal anode lead to a short life span and poor safety, seriously hindering the practical applications of lithium metal batteries. With a trisalt electrolyte design, an F-/N-containing inorganics-rich solid electrolyte interphase on a lithium anode is constructed, which is electrochemically and thermally stable over long-term cycles and safety abuse conditions. As a result, its Coulombic efficiency can be maintained over 98.98% for 400 cycles. An 85.0% capacity can be retained for coin-type full cells with a 3.14 mAh cm-2 LiNi0.5 Co0.2 Mn0.3 O2 cathode after 200 cycles and 1.0 Ah pouch-type full cells with a 4.0 mAh cm-2 cathode after 72 cycles. During the thermal runaway tests of a cycled 1.0 Ah pouch cell, the onset and triggering temperatures were increased from 70.8 °C and 117.4 °C to 100.6 °C and 153.1 °C, respectively, indicating a greatly enhanced safety performance. This work gives novel insights into electrolyte and interface design, potentially paving the way for high-energy-density, long-life-span, and thermally safe lithium metal batteries
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|a Journal Article
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|a dendrite
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|a lithium metal anodes
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|a pouch cells
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|a safety
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|a solid electrolyte interphase
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|a Yang, Shi-Jie
|e verfasserin
|4 aut
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|a Liu, Zaichun
|e verfasserin
|4 aut
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|a Guo, Jia-Xin
|e verfasserin
|4 aut
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| 700 |
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|a Jiang, Feng-Ni
|e verfasserin
|4 aut
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|a Jiang, Feng
|e verfasserin
|4 aut
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|a Xiong, Xiaosong
|e verfasserin
|4 aut
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|a Tang, Wen-Bo
|e verfasserin
|4 aut
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|a Yuan, Hong
|e verfasserin
|4 aut
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|a Huang, Jia-Qi
|e verfasserin
|4 aut
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|a Wu, Yuping
|e verfasserin
|4 aut
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| 700 |
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|a Zhang, Qiang
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 1 vom: 21. Jan., Seite e2307370
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:36
|g year:2024
|g number:1
|g day:21
|g month:01
|g pages:e2307370
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|u http://dx.doi.org/10.1002/adma.202307370
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