|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM360782280 |
| 003 |
DE-627 |
| 005 |
20231226083739.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2023 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202305845
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1202.xml
|
| 035 |
|
|
|a (DE-627)NLM360782280
|
| 035 |
|
|
|a (NLM)37578840
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a He, Siyang
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Photoinduced Mechanical Cloaking of Diarylethene-Crosslinked Microgels
|
| 264 |
|
1 |
|c 2023
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 12.10.2023
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status Publisher
|
| 520 |
|
|
|a © 2023 The Authors. Advanced Materials published by Wiley-VCH GmbH.
|
| 520 |
|
|
|a The serial connection of multiple stimuli-responses in polymer architectures enables the logically conjunctive gating of functional material processes on demand. Here, a photoswitchable diarylethene (DAE) acts as a crosslinker in poly(N-vinylcaprolactam) microgels and allows the light-induced shift of the volume phase-transition temperature (VPTT). While swollen microgels below the VPTT are susceptible to force and undergo breakage-aggregation processes, collapsed microgels above the VPTT stay intact in mechanical fields induced by ultrasonication. Within a VPTT shift regime, photoswitching of the DAE transfers microgels from the swollen to the collapsed state and thereby gates their response to force as demonstrated by the light-gated activation of an embedded fluorogenic mechanophore. This photoinduced mechanical cloaking system operates on the polymer topology level and is thereby principally universally applicable
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a mechanical properties
|
| 650 |
|
4 |
|a mechanochemistry
|
| 650 |
|
4 |
|a microgels
|
| 650 |
|
4 |
|a photoswitches
|
| 700 |
1 |
|
|a Schog, Simon
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chen, Ying
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ji, Yuxin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Panitz, Sinan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Richtering, Walter
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Göstl, Robert
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 41 vom: 17. Okt., Seite e2305845
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:35
|g year:2023
|g number:41
|g day:17
|g month:10
|g pages:e2305845
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202305845
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 35
|j 2023
|e 41
|b 17
|c 10
|h e2305845
|