|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM360715753 |
| 003 |
DE-627 |
| 005 |
20240125231900.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202305416
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1270.xml
|
| 035 |
|
|
|a (DE-627)NLM360715753
|
| 035 |
|
|
|a (NLM)37572077
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Yang, Wanli
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a High-Performance n-Type Polymeric Mixed Ionic-Electronic Conductors
|b The Impacts of Halogen Functionalization
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 25.01.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2023 Wiley-VCH GmbH.
|
| 520 |
|
|
|a Developing high-performance n-type polymer mixed ionic-electronic conductors (PMIECs) is a grand challenge, which largely determines their applications in vaious organic electronic devices, such as organic electrochemical transistors (OECTs) and organic thermoelectrics (OTEs). Herein, two halogen-functionalized PMIECs f-BTI2g-TVTF and f-BTI2g-TVTCl built from fused bithiophene imide dimer (f-BTI2) as the acceptor unit and halogenated thienylene-vinylene-thienylene (TVT) as the donor co-unit are reported. Compared to the control polymer f-BTI2g-TVT, the fluorinated f-BTI2g-TVTF shows lower-positioned lowest unoccupied molecular orbital (LUMO), improved charge transport property, and greater ion uptake capacity. Consequently, f-BTI2g-TVTF delivers a state-of-the-art µC* of 90.2 F cm-1 V-1 s-1 with a remarkable electron mobility of 0.41 cm2 V-1 s-1 in OECTs and an excellent power factor of 64.2 µW m-1 K-2 in OTEs. An OECT-based inverter amplifier is further demonstrated with voltage gain up to 148 V V-1 , which is among the highest values for OECT inverters. Such results shed light on the impacts of halogen atoms on developing high-performing n-type PMIECs
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a halogen functionalization
|
| 650 |
|
4 |
|a n-type polymer semiconductors
|
| 650 |
|
4 |
|a organic electrochemical transistors
|
| 650 |
|
4 |
|a organic thermoelectrics
|
| 650 |
|
4 |
|a polymeric mixed ionic-electronic conductors
|
| 700 |
1 |
|
|a Feng, Kui
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ma, Suxiang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Bin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Yimei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ding, Riqing
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Jeong, Sang Young
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Woo, Han Young
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chan, Paddy Kwok Leung
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Guo, Xugang
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 4 vom: 23. Jan., Seite e2305416
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:4
|g day:23
|g month:01
|g pages:e2305416
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202305416
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 4
|b 23
|c 01
|h e2305416
|