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231226s2024 xx |||||o 00| ||eng c |
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|a 10.1080/09593330.2023.2245541
|2 doi
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|a pubmed24n1513.xml
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|a (DE-627)NLM360591566
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|a (NLM)37559566
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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1 |
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|a Shang, Zhiguo
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Pyridine-bridged cobalt tetra-aminophthalocyanine to active peroxymonosulphate for efficient degrading carbamazepine
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|c 2024
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 26.08.2024
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|a Date Revised 26.08.2024
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a In this study, each cobalt tetra-aminophthalocyanine (CoTAPc) molecule was immobilised with four isonicotinic acid (INA) molecules by amide bonding, a novel and highly efficient catalyst pyridine-bridged cobalt tetra-aminophthalocyanine (CoTAPc-TINA) was synthesised. The introduction of INA molecules promoted CoTAPc to expose more active sites, and increased the electron cloud density of cobalt ions promoting O-O bond homolysis of PMS to generate more active species, which significantly enhanced catalytic activity. With the pharmaceutical of carbamazepine (CBZ) as model pollutant, 0.1 g/L CoTAPc-TINA in dark in the presence of 0.4 mM PMS, 98.8% CBZ was removed within 10 min. However, under the same conditions the removed of CBZ was only 58.9% by CoTAPc/PMS system. Radical capture experiments combined electron paramagnetic resonance technology demonstrate that hydroxyl radicals, sulphate radicals, superoxide radicals and singlet oxygen are the main active species in the CoTAPc-TINA/PMS system. As the reaction proceeded, all aromatic intermediates were transformed to small molecular acids by these active species. This investigation provided a new insight for application of metal phthalocyanine in wastewater treatment
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|a Journal Article
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|a Pyridine-bridged
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|a cobalt tetra-aminophthalocyanine
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4 |
|a degradation pathway
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4 |
|a isonicotinic acid
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4 |
|a peroxymonosulphate
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|a Carbamazepine
|2 NLM
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|a 33CM23913M
|2 NLM
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| 650 |
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|a Water Pollutants, Chemical
|2 NLM
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|a peroxymonosulfate
|2 NLM
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| 650 |
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|a 22047-43-4
|2 NLM
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| 650 |
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7 |
|a Pyridines
|2 NLM
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| 650 |
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|a Cobalt
|2 NLM
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| 650 |
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7 |
|a 3G0H8C9362
|2 NLM
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| 650 |
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7 |
|a Indoles
|2 NLM
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| 650 |
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|a Peroxides
|2 NLM
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| 700 |
1 |
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|a Zhu, Zhexin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wang, Gangqiang
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Lu, Wangyang
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wu, Bingyao
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Li, Qijian
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Environmental technology
|d 1993
|g 45(2024), 21 vom: 13. Aug., Seite 4230-4242
|w (DE-627)NLM098202545
|x 1479-487X
|7 nnns
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| 773 |
1 |
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|g volume:45
|g year:2024
|g number:21
|g day:13
|g month:08
|g pages:4230-4242
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|u http://dx.doi.org/10.1080/09593330.2023.2245541
|3 Volltext
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|d 45
|j 2024
|e 21
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|h 4230-4242
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