|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM360551521 |
| 003 |
DE-627 |
| 005 |
20240425232328.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202306480
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1386.xml
|
| 035 |
|
|
|a (DE-627)NLM360551521
|
| 035 |
|
|
|a (NLM)37555527
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Ding, Jie
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Room-Temperature Chemoselective Hydrogenation of Nitroarene Over Atomic Metal-Nonmetal Catalytic Pair
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 25.04.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2023 Wiley‐VCH GmbH.
|
| 520 |
|
|
|a Constructing atomic catalytic pair emerges as an attractive strategy to achieve better catalytic performance. Herein, an atomic Ir1─P1/NPG catalyst with asymmetric Ir─N2P1 sites that delivers superb activity and selectivity for hydrogenation of various functionalized nitrostyrene is reported. In the hydrogenation reaction of 3-nitrostyrene, Ir1─P1/NPG (NPG refers to N, P-codoped graphene) shows a turnover frequency of 1197 h-1, while the reaction cannot occur over Ir1/NG (NG refers to N-doped graphene). Compared to Ir1/NG, the charge density of the Ir site in Ir1─P1/NPG is greatly elevated, which is conducive to H2 dissociation. Moreover, as revealed by density functional theory calculations and poisoning experiments, the P site in Ir1─P1/NPG is found able to bind nitrostyrene, while the neighboring Ir site provides H to reduce the nitro group in chemoselective hydrogenation of nitrostyrene. This work offers a successful example of establishing atomic catalytic pair for driving important chemical reactions, paving the way for the development of more advanced catalysts to further improve the catalytic performance
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a atomically dispersed
|
| 650 |
|
4 |
|a catalytic pairs
|
| 650 |
|
4 |
|a heterogeneous catalysis
|
| 650 |
|
4 |
|a hydrogenation
|
| 650 |
|
4 |
|a nitrostyrene
|
| 700 |
1 |
|
|a Li, Fuhua
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Jincheng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Qi, Haifeng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wei, Zhiming
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Su, Chenliang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Hong Bin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhai, Yueming
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Bin
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 17 vom: 25. Apr., Seite e2306480
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:17
|g day:25
|g month:04
|g pages:e2306480
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202306480
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 17
|b 25
|c 04
|h e2306480
|