Color-Tunable, Excitation-Dependent, and Water Stimulus-Responsive Room-Temperature Phosphorescence Cellulose for Versatile Applications
© 2023 Wiley-VCH GmbH.
| Publié dans: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 46 vom: 27. Nov., Seite e2304032 |
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| Auteur principal: | |
| Autres auteurs: | , , , , |
| Format: | Article en ligne |
| Langue: | English |
| Publié: |
2023
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| Accès à la collection: | Advanced materials (Deerfield Beach, Fla.) |
| Sujets: | Journal Article cellulose multicomponent reaction room-temperature phosphorescence smart-response materials |
| Résumé: | © 2023 Wiley-VCH GmbH. Smart-response materials with ultralong room-temperature phosphorescence (RTP) are highly desirable, but they have rarely been described, especially those originating from sustainable polymers. Herein, a variety of cellulose derivatives with 1,4-dihydropyridine (DHP) rings are synthesized through the Hantzsch reaction, giving impressive RTP with a long lifetime of up to 1251 ms. Specifically, the introduction of acetoacetyl groups and DHP rings promotes the spin-orbit coupling and intersystem crossing process; and multiple interactions between cellulose induce clustering and inhibit the nonradiative transitions, boosting long-live RTP. Furthermore, the resulting transparent and flexible cellulose films also exhibit excitation-dependent and color-tunable afterglows by introducing different extended aromatic groups. More interestingly, the RTP performance of these films is sensitive to water and can be repeated in response to wet/dry stimuli. Inspired by these advantages, the RTP cellulose demonstrates advanced applications in information encryption and anti-counterfeiting. This work not only enriches the photophysical properties of cellulose but also provides a versatile platform for the development of sustainable afterglows |
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| Description: | Date Revised 12.02.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202304032 |