Preparation and characterization of calcined Ni/Mo hydrotalcite for the effective removal of lead from wastewater
In this investigation, calcined Ni/Mo hydrotalcite was prepared via co-precipitation method and used as a sorbent for efficient removal of lead from aqueous solutions. The Pb2+ removal efficiency reached 99% at pH 6 and a sorbent dose of 2 g/L. The equilibrium data were satisfactorily fitted by the...
| Veröffentlicht in: | Environmental technology. - 1993. - 45(2024), 20 vom: 08. Aug., Seite 4096-4115 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2024
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| Zugriff auf das übergeordnete Werk: | Environmental technology |
| Schlagworte: | Journal Article Kinetic layered double hydroxides lead sorption wastewater Lead 2P299V784P hydrotalcite 17432CG1KU mehr... |
| Zusammenfassung: | In this investigation, calcined Ni/Mo hydrotalcite was prepared via co-precipitation method and used as a sorbent for efficient removal of lead from aqueous solutions. The Pb2+ removal efficiency reached 99% at pH 6 and a sorbent dose of 2 g/L. The equilibrium data were satisfactorily fitted by the Langmuir and Hill models with a maximum capacity of 196.87 mg/g, indicating the monolayer sorption for lead over calcined Ni/Mo hydrotalcite. The Pb2+ sorption kinetic follows a pseudo-second-order reaction due to high correlation coefficients (R2 > 0.99), while the Boyd's plots confirm the external mass transfer as the rate-limiting step in the Pb2+ sorption. The temperature effect indicated a spontaneous and exothermic Pb2+ uptake. Mechanisms involved in the removal process include surface precipitation, diffusion into the solid pores and isomorphic substitution with Ni2+ of the sheets. The results showed excellent selectivity for Pb2+ removal from multi-divalent cation solutions and good reusability of the sorbent for up to 10 consecutive sorption-regeneration cycles without significant loss of the removal efficiency. As an application, the treatment of wastewater containing Pb2+, generated from the battery industry has been undertaken. The Pb2+ concentration was reduced from 5.7 to 0.6 mg/L, corresponding to an abatement of 89.5%. Therefore, the sorption using calcined Ni/Mo hydrotalcite is an efficient and suitable method for the elimination of Pb2+ |
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| Beschreibung: | Date Completed 23.07.2024 Date Revised 23.07.2024 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1479-487X |
| DOI: | 10.1080/09593330.2023.2241120 |