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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.3c00989
|2 doi
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|a pubmed24n1196.xml
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|a (DE-627)NLM358841933
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|a (NLM)37382911
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Zhao, Chuanqing
|e verfasserin
|4 aut
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|a Thermally Insulating SiO2/PSA Composite Aerogels with Heat Resistance and Mechanical Properties via the Thiol-Yne Click Reaction
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 11.07.2023
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|a Date Revised 18.07.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Polymer-reinforced silica aerogels are thermally insulating materials employed to enhance mechanical properties; however, they exhibit low heat stability and require a complex production process. The main body of this work concerns the synthesis of silicon-containing polyarylacetylene (PSA) resin, which has exceptional thermal properties and is used to strengthen the gel skeleton and significantly improve the heat resistance of the polymer reinforcement phase. The honeycomb-like porous SiO2/PSA aerogels derived from directional freezing were obtained via click reaction, gel aging, freeze-drying, and curing without the requirement for time-consuming solvent replacement. The prepared SiO2/PSA aerogel is low density (∼0.3 g/cm3) and high porosity (∼80%), which provides the material with low levels of thermal conductivity (∼0.06 W/m·K) and excellent thermal insulation performance. When compared to the majority of polymer aerogels and aerogel-like materials, the prepared SiO2/PSA aerogels have high Td5 (∼460 °C) and Yr800 (∼80%) and compressive strength (compression strength > 1.5 MPa). SiO2/PSA composite aerogel has numerous functions in areas where materials must withstand extremely elevated temperatures, such as the aerospace industry
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|a Journal Article
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|a Qiao, Fangke
|e verfasserin
|4 aut
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|a Ji, Jiawei
|e verfasserin
|4 aut
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|a Deng, Shifeng
|e verfasserin
|4 aut
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|a Qi, Huimin
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 39(2023), 27 vom: 11. Juli, Seite 9468-9475
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:39
|g year:2023
|g number:27
|g day:11
|g month:07
|g pages:9468-9475
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|u http://dx.doi.org/10.1021/acs.langmuir.3c00989
|3 Volltext
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