Custom-designed 3D printed feed spacers and TFN membranes with MIL-101(Fe) for water recovery by forward osmosis

In this work, a dual-pronged approach- (i) novel thin-film nanocomposite polyether sulfone (PES) membrane with MIL-101 (Fe) and (ii) 3D printed spacers were explored to enhance water recovery by forward osmosis. The concentration of PES, pore former, draw solution, and MIL-101(Fe) was optimised for...

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Veröffentlicht in:Environmental technology. - 1993. - 45(2024), 19 vom: 12. Juli, Seite 3778-3790
1. Verfasser: Suresh, K (VerfasserIn)
Weitere Verfasser: Nambikkattu, Jenny, Kaleekkal, Noel Jacob, Lawrence, K Deepak
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article MIL-101(Fe): 3D printed feed spacer Thin-film nanocomposite membrane forward osmosis oily water Membranes, Artificial Metal-Organic Frameworks MIL-101 Sulfones Wastewater mehr... polyether sulfone 25667-42-9 Polymers
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520 |a In this work, a dual-pronged approach- (i) novel thin-film nanocomposite polyether sulfone (PES) membrane with MIL-101 (Fe) and (ii) 3D printed spacers were explored to enhance water recovery by forward osmosis. The concentration of PES, pore former, draw solution, and MIL-101(Fe) was optimised for maximum pure water flux (PWF) and minimum specific reverse solute flux (SRSF). The best membrane exhibited a PWF of 7.52 Lm-2 h-1 and an SRSF of 0.33 ± 0.03 gL-1 using 1.5 M NaCl and DI water feed. The M22 membrane with the diamond-type spacer demonstrated a PWF of 2.53 Lm-2 h-1 and SRSF of 0.75 gL-1 for emulsified oily wastewater feed. The novel spacer design imparted significant turbulence to the feed flow and a lower foulant resistance of 1.3 m-1 as compared to the ladder type (1.5 m-1) or commercial spacer (1.7 m-1). This arrangement could recover 19% pure water within 12 h of operation (98% oil rejection) with a ∼ 94% flux recovery after hydraulic wash 
650 4 |a Journal Article 
650 4 |a MIL-101(Fe): 3D printed feed spacer 
650 4 |a Thin-film nanocomposite membrane 
650 4 |a forward osmosis 
650 4 |a oily water 
650 7 |a Membranes, Artificial  |2 NLM 
650 7 |a Metal-Organic Frameworks  |2 NLM 
650 7 |a MIL-101  |2 NLM 
650 7 |a Sulfones  |2 NLM 
650 7 |a Wastewater  |2 NLM 
650 7 |a polyether sulfone  |2 NLM 
650 7 |a 25667-42-9  |2 NLM 
650 7 |a Polymers  |2 NLM 
700 1 |a Nambikkattu, Jenny  |e verfasserin  |4 aut 
700 1 |a Kaleekkal, Noel Jacob  |e verfasserin  |4 aut 
700 1 |a Lawrence, K Deepak  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Environmental technology  |d 1993  |g 45(2024), 19 vom: 12. Juli, Seite 3778-3790  |w (DE-627)NLM098202545  |x 1479-487X  |7 nnns 
773 1 8 |g volume:45  |g year:2024  |g number:19  |g day:12  |g month:07  |g pages:3778-3790 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2023.2231142  |3 Volltext 
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