Revealing the Dynamic Behavior of Active Sites on Acid-Functionalized CeO2 Catalysts for NOx Reduction
Unraveling the dynamics of the active sites upon CeO2-based catalysts in selective catalytic reduction of nitrogen oxides by ammonia (NH3-SCR) is challenging. In this work, we prepared tungsten-acidified and sulfated CeO2 catalysts and used operando spectroscopy to reveal the dynamics of acid sites...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 39(2023), 25 vom: 27. Juni, Seite 8889-8899 |
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| Weitere Verfasser: | , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2023
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | Unraveling the dynamics of the active sites upon CeO2-based catalysts in selective catalytic reduction of nitrogen oxides by ammonia (NH3-SCR) is challenging. In this work, we prepared tungsten-acidified and sulfated CeO2 catalysts and used operando spectroscopy to reveal the dynamics of acid sites and redox sites on catalysts during NH3-SCR reaction. We found that both Lewis and Brønsted acid sites are needed to participate in the catalytic reaction. Notably, Brønsted acid sites are the main active sites after a tungsten-acidified or sulfated treatment, and the change of Brønsted acid sites significantly affects the NOx removal. Moreover, acid functionalization promotes the cerium species cycle between Ce4+ and Ce3+ for the NOx reduction. This work is critical to deeply understanding the natural properties of active sites, and it also provides new insights into the mechanism for NH3-SCR over CeO2-based catalysts |
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| Beschreibung: | Date Completed 27.06.2023 Date Revised 27.06.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.3c01033 |