Crack-Free Structural Color Materials Prepared without Disrupting the Particle Arrangement by Controlling the Internal Stress Relaxation and Interactions of the Melanin Particles

In fabricating structural color materials with assembled colloidal particles, there is a trade-off between the internal stresses acting on the particles and the interactions between the particles during solvent volatilization. It is crucial to fabricate crack-free materials that maintain the periodi...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 39(2023), 25 vom: 27. Juni, Seite 8725-8736
1. Verfasser: Urase, Mai (VerfasserIn)
Weitere Verfasser: Maejima, Yui, Watanabe, Taku, Kishikawa, Keiki, Fudouzi, Hiroshi, Kohri, Michinari
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Crack-Free Structural Color Materials Prepared without Disrupting the Particle Arrangement by Controlling the Internal Stress Relaxation and Interactions of the Melanin Particles 
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520 |a In fabricating structural color materials with assembled colloidal particles, there is a trade-off between the internal stresses acting on the particles and the interactions between the particles during solvent volatilization. It is crucial to fabricate crack-free materials that maintain the periodic arrangements of the particles by understanding the mechanism for crack initiation. Here, we focused on the composition and additives of melanin particle dispersions to obtain crack-free structural color materials without disturbing the particle arrangements. The use of a water/ethanol mixture as a dispersant effectively reduced the internal stresses of the particles during solvent evaporation. Furthermore, the addition of low-molecular-weight, low-volatility ionic liquids ensured that the arrangement and interactions of the particles were maintained after solvent volatilization. Optimization of the composition and additives of the dispersion made it possible to achieve crack-free melanin-based structural color materials while maintaining vivid, angular-dependent color tones 
650 4 |a Journal Article 
700 1 |a Maejima, Yui  |e verfasserin  |4 aut 
700 1 |a Watanabe, Taku  |e verfasserin  |4 aut 
700 1 |a Kishikawa, Keiki  |e verfasserin  |4 aut 
700 1 |a Fudouzi, Hiroshi  |e verfasserin  |4 aut 
700 1 |a Kohri, Michinari  |e verfasserin  |4 aut 
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