Toughening CO2 -Derived Copolymer Elastomers Through Ionomer Networking
© 2023 The Authors. Advanced Materials published by Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 36 vom: 19. Sept., Seite e2302825 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2023
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article bio-derived materials carbon dioxide epoxide ionomers lactone polycarbonate polyester ring-opening copolymerization ring-opening polymerization |
| Zusammenfassung: | © 2023 The Authors. Advanced Materials published by Wiley-VCH GmbH. Utilizing carbon dioxide (CO2 ) to make polycarbonates through the ring-opening copolymerization (ROCOP) of CO2 and epoxides valorizes and recycles CO2 and reduces pollution in polymer manufacturing. Recent developments in catalysis provide access to polycarbonates with well-defined structures and allow for copolymerization with biomass-derived monomers; however, the resulting material properties are underinvestigated. Here, new types of CO2 -derived thermoplastic elastomers (TPEs) are described together with a generally applicable method to augment tensile mechanical strength and Young's modulus without requiring material re-design. These TPEs combine high glass transition temperature (Tg ) amorphous blocks comprising CO2 -derived poly(carbonates) (A-block), with low Tg poly(ε-decalactone), from castor oil, (B-block) in ABA structures. The poly(carbonate) blocks are selectively functionalized with metal-carboxylates where the metals are Na(I), Mg(II), Ca(II), Zn(II) and Al(III). The colorless polymers, featuring <1 wt% metal, show tunable thermal (Tg ), and mechanical (elongation at break, elasticity, creep-resistance) properties. The best elastomers show >50-fold higher Young's modulus and 21-times greater tensile strength, without compromise to elastic recovery, compared with the starting block polymers. They have wide operating temperatures (-20 to 200 °C), high creep-resistance and yet remain recyclable. In the future, these materials may substitute high-volume petrochemical elastomers and be utilized in high-growth fields like medicine, robotics, and electronics |
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| Beschreibung: | Date Revised 19.12.2023 published: Print-Electronic ErratumIn: Adv Mater. 2023 Dec 19;:e2312069. - PMID 38111982 Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202302825 |