Construct of an Electrodeposited Cobalt-Molybdenum Film and Evaluation of Its Efficiency in Hydrogen Evolution

Hydrogen is a valuable clean energy source, and electrolysis to produce hydrogen from water is a crucial component. However, a major problem of hydrogen generation by electrolysis is its large overpotential and poor economics. To reduce the overpotential, we mainly use nickel foam and Co-Mo ions as...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 39(2023), 22 vom: 06. Juni, Seite 7605-7612
1. Verfasser: Zhang, Yao (VerfasserIn)
Weitere Verfasser: Wang, Wenjing, Chen, Xinliang, Li, Qiaoling, Yu, Chengcheng
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Hydrogen is a valuable clean energy source, and electrolysis to produce hydrogen from water is a crucial component. However, a major problem of hydrogen generation by electrolysis is its large overpotential and poor economics. To reduce the overpotential, we mainly use nickel foam and Co-Mo ions as feedstock and create an efficient catalytic material by electrodeposition. The Co-Mo interaction improves the current efficiency. In 1 mol/L NaOH solution, the overpotential of the Co-Mo-NF composites was low when the current density is -10 mA/cm2, with the best value reaching 45.3 mV, which is less than those of Co-NF (94.4 mV) and Mo-NF (88.2 mV). All deposits had similar Tafel slopes in the 77.9 mV/decade range. The catalyst does not just have a favorable effect on hydrogen formation but also has a surprisingly high double-layer capacitance (up to 180 mF/cm2) and good stability. This research provides an impactful approach for developing a non-precious metal HER catalyst for industrial hydrogen production 
650 4 |a Journal Article 
700 1 |a Wang, Wenjing  |e verfasserin  |4 aut 
700 1 |a Chen, Xinliang  |e verfasserin  |4 aut 
700 1 |a Li, Qiaoling  |e verfasserin  |4 aut 
700 1 |a Yu, Chengcheng  |e verfasserin  |4 aut 
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