|
|
|
|
| LEADER |
01000caa a22002652c 4500 |
| 001 |
NLM356748308 |
| 003 |
DE-627 |
| 005 |
20250304183540.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2023 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202210671
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n1188.xml
|
| 035 |
|
|
|a (DE-627)NLM356748308
|
| 035 |
|
|
|a (NLM)37171977
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Zou, Jinshuo
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Revisiting the Role of Discharge Products in Li-CO2 Batteries
|
| 264 |
|
1 |
|c 2023
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 08.12.2023
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2023 The Authors. Advanced Materials published by Wiley-VCH GmbH.
|
| 520 |
|
|
|a Rechargeable lithium-carbon dioxide (Li-CO2 ) batteries are promising devices for CO2 recycling and energy storage. However, thermodynamically stable and electrically insulating discharge products (DPs) (e.g., Li2 CO3 ) deposited at cathodes require rigorous conditions for completed decomposition, resulting in large recharge polarization and poor battery reversibility. Although progress has been achieved in cathode design and electrolyte optimization, the significance of DPs is generally underestimated. Therefore, it is necessary to revisit the role of DPs in Li-CO2 batteries to boost overall battery performance. Here, a critical and systematic review of DPs in Li-CO2 batteries is reported for the first time. Fundamentals of reactions for formation and decomposition of DPs are appraised; impacts on battery performance including overpotential, capacity, and stability are demonstrated; and the necessity of discharge product management is highlighted. Practical in situ/operando technologies are assessed to characterize reaction intermediates and the corresponding DPs for mechanism investigation. Additionally, achievable control measures to boost the decomposition of DPs are evidenced to provide battery design principles and improve the battery performance. Findings from this work will deepen the understanding of electrochemistry of Li-CO2 batteries and promote practical applications
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Review
|
| 650 |
|
4 |
|a CO2 recycling
|
| 650 |
|
4 |
|a Li-CO2 batteries
|
| 650 |
|
4 |
|a discharge products
|
| 650 |
|
4 |
|a energy storage
|
| 650 |
|
4 |
|a product formation and decomposition
|
| 700 |
1 |
|
|a Liang, Gemeng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Fangli
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Shilin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Davey, Kenneth
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Guo, Zaiping
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 49 vom: 01. Dez., Seite e2210671
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
|
| 773 |
1 |
8 |
|g volume:35
|g year:2023
|g number:49
|g day:01
|g month:12
|g pages:e2210671
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202210671
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 35
|j 2023
|e 49
|b 01
|c 12
|h e2210671
|