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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202302325
|2 doi
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|a pubmed24n1188.xml
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|a (DE-627)NLM356690393
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|a (NLM)37166138
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Guo, Chang
|e verfasserin
|4 aut
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|a Intrinsic Descriptor Guided Noble Metal Cathode Design for Li-CO2 Battery
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 17.08.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2023 Wiley-VCH GmbH.
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|a To date, the effect of noble metal (NM) electronic structures on CO2 reaction activity remains unknown, and explicit screening criteria are still lacking for designing highly efficient catalysts in CO2 -breathing batteries. Herein, by preferentially considering the decomposition of key intermediate Li2 CO3 , an intrinsic descriptor constituted of the d x 2 - y 2 ${{\rm{d}}}_{{x}^2 - {y}^2}$ orbital states and the electronegativity for predicting high-performance cathode material are discovered. As a demonstration, a series of graphene-supported noble metals (NMG) as cathodes are fabricated via a fast laser scribing technique. Consistent with the preliminary prediction, Pd@G exhibits an ultralow overpotential (0.41 V), along with superior cycling performance up to 1400 h. Moreover, the overall thermodynamic reaction pathways on NM@G confirm the reliability of the established intrinsic descriptor. This basic finding of the relationship between the electronic properties of noble metal cathodes and the performance of Li-CO2 batteries provides a novel avenue for designing remarkably efficient cathode materials for metal-CO2 batteries
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|a Journal Article
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|a CO2 reduction/evolution reaction
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|a Li-CO2 batteries
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|a intrinsic descriptors
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|a noble-based catalysts
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1 |
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|a Zhang, Fuli
|e verfasserin
|4 aut
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1 |
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|a Han, Xiao
|e verfasserin
|4 aut
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1 |
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|a Zhang, Lipeng
|e verfasserin
|4 aut
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1 |
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|a Hou, Qian
|e verfasserin
|4 aut
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1 |
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|a Gong, Lele
|e verfasserin
|4 aut
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1 |
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|a Wang, Jincheng
|e verfasserin
|4 aut
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1 |
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|a Xia, Zhenhai
|e verfasserin
|4 aut
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1 |
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|a Hao, Jianhua
|e verfasserin
|4 aut
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| 700 |
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|a Xie, Keyu
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 33 vom: 18. Aug., Seite e2302325
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:35
|g year:2023
|g number:33
|g day:18
|g month:08
|g pages:e2302325
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|u http://dx.doi.org/10.1002/adma.202302325
|3 Volltext
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