Humic acid recovery from stabilized leachate : Characterization and interference with chemical oxygen demand-colour removal

Heterogeneous combinations of organic compounds (humic acid (HA) and fulvic acid) are the prime factor for the high concentration of colour and chemical oxygen demand (COD) in semi-aerobic stabilized landfill leachate. These organics are less biodegradable and cause a severe threat to environmental...

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Veröffentlicht in:Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA. - 1991. - 41(2023), 10 vom: 23. Okt., Seite 1584-1593
1. Verfasser: Ahmed, Zaber (VerfasserIn)
Weitere Verfasser: Yusoff, Mohd Suffian, Kamal, Nurul Hana Mokhtar, Aziz, Hamidi Abdul
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA
Schlagworte:Journal Article FTIR Stabilized leachate UV–vis absorbance XPS humic acid microfiltration–centrifugation refractory organics Humic Substances Water Pollutants, Chemical
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520 |a Heterogeneous combinations of organic compounds (humic acid (HA) and fulvic acid) are the prime factor for the high concentration of colour and chemical oxygen demand (COD) in semi-aerobic stabilized landfill leachate. These organics are less biodegradable and cause a severe threat to environmental elements. Microfiltration and centrifugation processes were applied in this study to investigate the HA removal from stabilized leachate samples and its corresponding interference with COD and colour. The three-stage extraction process recovered a maximum of 1412 ± 2.5 mg/L (Pulau Burung landfill site (PBLS) leachate), 1510 ± 1.5 mg/L (Alor Pongsu landfill site (APLS leachate) at pH 1.5 and 1371 ± 2.5 mg/L (PBLS) and 1451 ± 1.5 mg/L (APLS) of HA (about 42% of the total COD concentration) at pH 2.5, which eventually indicates the process efficiency. Comparative characteristics analysis of recovered HA by scanning electron microscopy, energy-dispersive X-ray, X-ray photoelectron spectroscopy, and Fourier transform infrared significantly indicate the existence of identical elements in the recovered HA compared with the previous studies. The higher reduction (around 37%) in ultraviolet (UV) absorbance values (UV254 and UV280) in the final effluent indicates the elimination of aromaticity and conjugated double-bond compounds from leachate. Moreover, 36 and 39% COD and 39 and 44% colour removal exhibit substantial interference 
650 4 |a Journal Article 
650 4 |a FTIR 
650 4 |a Stabilized leachate 
650 4 |a UV–vis absorbance 
650 4 |a XPS 
650 4 |a humic acid 
650 4 |a microfiltration–centrifugation 
650 4 |a refractory organics 
650 7 |a Humic Substances  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
700 1 |a Yusoff, Mohd Suffian  |e verfasserin  |4 aut 
700 1 |a Kamal, Nurul Hana Mokhtar  |e verfasserin  |4 aut 
700 1 |a Aziz, Hamidi Abdul  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA  |d 1991  |g 41(2023), 10 vom: 23. Okt., Seite 1584-1593  |w (DE-627)NLM098164791  |x 1096-3669  |7 nnns 
773 1 8 |g volume:41  |g year:2023  |g number:10  |g day:23  |g month:10  |g pages:1584-1593 
856 4 0 |u http://dx.doi.org/10.1177/0734242X231160687  |3 Volltext 
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