|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM356516946 |
| 003 |
DE-627 |
| 005 |
20231226070631.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2023 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202301096
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1188.xml
|
| 035 |
|
|
|a (DE-627)NLM356516946
|
| 035 |
|
|
|a (NLM)37148533
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Tan, Xinghua
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Imitating Architectural Mortise-Tenon Structure for Stable Ni-Rich Layered Cathodes
|
| 264 |
|
1 |
|c 2023
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 20.10.2023
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2023 Wiley-VCH GmbH.
|
| 520 |
|
|
|a Ni-rich layered oxides are the most promising cathodes for Li-ion batteries, but chemo-mechanical failures during cycling and large first-cycle capacity loss hinder their applications in high-energy batteries. Herein, by introducing spinel-like mortise-tenon structures into the layered phase of LiNi0.8 Co0.1 Mn0.1 O2 (NCM811), the adverse volume variations in cathode materials can be significantly suppressed. Meanwhile, these mortise-tenon structures play the role of the expressway for fast lithium-ion transport, which is substantiated by experiments and calculations. Moreover, the particles with mortise-tenon structures usually terminate with the most stable (003) facet. The new cathode exhibits a discharge capacity of 215 mAh g-1 at 0.1 C with an initial Coulombic efficiency of 97.5%, and capacity retention of 82.2% after 1200 cycles at 1 C. This work offers a viable lattice engineering to address the stability and low initial Coulombic efficiency of the Ni-rich layered oxides, and facilitates the implementation of Li-ion batteries with high-energy density and long durability
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Ni-rich layered cathodes
|
| 650 |
|
4 |
|a fast lithium-ion transport
|
| 650 |
|
4 |
|a initial Coulombic efficiency
|
| 650 |
|
4 |
|a mortise-tenon structures
|
| 650 |
|
4 |
|a volume variations
|
| 700 |
1 |
|
|a Chen, Zhefeng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Tongchao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Yongxin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Mingjian
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Shunning
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chu, Weiguo
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Kang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Peihua
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Pan, Feng
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 32 vom: 06. Aug., Seite e2301096
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:35
|g year:2023
|g number:32
|g day:06
|g month:08
|g pages:e2301096
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202301096
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 35
|j 2023
|e 32
|b 06
|c 08
|h e2301096
|