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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202301772
|2 doi
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|a pubmed24n1188.xml
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|a (DE-627)NLM356516644
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|a (NLM)37148503
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Xiao, Yaoyao
|e verfasserin
|4 aut
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|a Construction of Ultrastable Ultrathin Black Phosphorus Nanodisks Hybridized with Fe3 O4 Nanoclusters and Iron (V)-Oxo Complex for Efficient Potassium Storage
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 01.07.2023
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|a published: Print-Electronic
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|a Citation Status Publisher
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|a © 2023 Wiley-VCH GmbH.
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|a The practical application of metalloid black phosphorus (BP) based anodes for potassium ion batteries is mainly impeded by its instability in air and irreversible/sluggish potassium storage behaviors. Herein, a 2D composite is purposefully conceptualized, where ultrathin BP nanodisks with Fe3 O4 nanoclusters are hybridized with Lewis acid iron (V)-oxo complex (FC) nanosheets (denoted as BPFe3 O4 -NCs@FC). The introduced electron coordinate bridge between FC and BP, and hydrophobic surface of FC synergistically assure that BP@Fe3 O4 -NCs@FC is ultrastable in humid air. With the purposeful structural and componential design, the resultant BP@Fe3 O4 -NCs@FC anode is endowed with appealing electrochemical performance in terms of reversible capacity, rate behavior, and long-duration cycling stability in both half and full cells. Furthermore, the underlying formation and potassium-storage mechanisms of BP@Fe3 O4 -NCs@FC are tentatively proposed. The in-depth insights here will provide a crucial understanding in rational exploration of advanced anodes for next-generation PIBs
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|a Journal Article
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|a Fe(V)-oxo complex
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|a Fe3O4 nanoclusters
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|a anodes
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|a potassium-storage mechanism
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|a ultrastable black phosphorus
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|a Liu, Fusheng
|e verfasserin
|4 aut
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|a Shi, Huan
|e verfasserin
|4 aut
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|a Hou, Linrui
|e verfasserin
|4 aut
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|a Qin, Guohui
|e verfasserin
|4 aut
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|a Yuan, Changzhou
|e verfasserin
|4 aut
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|a Lou, Xiong Wen David
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g (2023) vom: 06. Mai, Seite e2301772
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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|g year:2023
|g day:06
|g month:05
|g pages:e2301772
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|u http://dx.doi.org/10.1002/adma.202301772
|3 Volltext
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