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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202302353
|2 doi
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|a pubmed24n1188.xml
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|a (DE-627)NLM356491692
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|a (NLM)37145988
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
1 |
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|a Deng, Dan
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Ion Tunnel Matrix Initiated Oriented Attachment for Highly Utilized Zn Anodes
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Revised 17.08.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2023 Wiley-VCH GmbH.
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|a Metallic zinc is an ideal anode for aqueous energy storage; however, Zn anodes suffer from nonhomogeneous deposition, low reversibility, and dendrite formation; these lead to an overprovision of zinc metal in full cells. Herein, oriented-attachment-regulated Zn stacking initiated through a trapping-then-planting process with a high zinc utilization rate (ZUR) is reported. Due to the isometric topology features of cubic-type Prussian blue analog (PBA), the initial Zn plating occurs at specific sites with equal spacing of ≈5 Å in the direction perpendicular to the substrate; the trace amount of zinc ions trapped in tunnel matrix provides nuclei for the oriented attachment of Zn (002) deposits. As a result, the PBA-decorated substrate delivers high reversibility of dendrite-free zinc plating/stripping for more than 6600 cycles (1320 h) and achieves an average Coulombic efficiency (CE) of 99.5% at 5 mA cm-2 with 100% ZUR. Moreover, the anode-limited full cell with a low negative-positive electrode ratio (N/P) of 1.2 can be operated stably for 360 cycles, displaying an energy density of 214 Wh kg-1 ; this greatly exceeds commercial aqueous batteries. This work provides a proof of concept design of metal anodes with a high utilization ratio and a practical method for developing high-energy-density batteries
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|a Journal Article
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|a Prussian blue analog
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|a aqueous zinc-ion batteries
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|a high zinc utilization rate
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|a oriented attachment
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|a zinc-metal anodes
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1 |
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|a Fu, Kai
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Yu, Ruohan
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhu, Jiao
|e verfasserin
|4 aut
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1 |
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|a Cai, Hongwei
|e verfasserin
|4 aut
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1 |
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|a Zhang, Xiangchen
|e verfasserin
|4 aut
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1 |
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|a Wu, Jinsong
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Luo, Wen
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Mai, Liqiang
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 33 vom: 25. Aug., Seite e2302353
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
1 |
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|g volume:35
|g year:2023
|g number:33
|g day:25
|g month:08
|g pages:e2302353
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|u http://dx.doi.org/10.1002/adma.202302353
|3 Volltext
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