Multiple-Stimuli-Responsive Surfactant-Free Microemulsions Based on Hydrophobic Deep Eutectic Solvents
Hydrophobic deep eutectic solvents (HDESs) have been applied to colloidal systems such as microemulsions, despite the development of stimulus-responsive HDESs still being in a preliminary stage. Here, menthol and indole were hydrogen bonded to form CO2-responsiveness HDES. A surfactant-free microemu...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 39(2023), 19 vom: 16. Mai, Seite 6730-6739 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2023
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | Hydrophobic deep eutectic solvents (HDESs) have been applied to colloidal systems such as microemulsions, despite the development of stimulus-responsive HDESs still being in a preliminary stage. Here, menthol and indole were hydrogen bonded to form CO2-responsiveness HDES. A surfactant-free microemulsion constituted of HDES (menthol-indole) as the hydrophobic phase, water as the hydrophilic phase, and ethanol as the double solvent was demonstrated to be CO2- and temperature-responsive. Dynamic light scattering (DLS) proved the single-phase region of the phase diagram, while conductivity and polarity probing techniques confirmed the kind of microemulsion. The ternary phase diagram and DLS methods were used to investigate the responsiveness of CO2 and effect temperature on the microemulsion drop size and behavior of the phase of the HDES/water/ethanol microemulsion. The findings revealed that when temperature increased, the homogeneous phase region increased. The droplet size in the homogeneous phase region of the associated microemulsion may be reversibly and accurately adjusted by adjusting the temperature. Surprisingly, a slight temperature change can cause a significant phase inversion. Furthermore, in the system, there was no demulsification in time for the CO2/N2 responsiveness process but rather the production of a homogeneous and pellucid aqueous solution |
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| Beschreibung: | Date Completed 16.05.2023 Date Revised 16.05.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.3c00205 |