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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.3c00032
|2 doi
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|a pubmed24n1185.xml
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|a (DE-627)NLM355791625
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|a (NLM)37075327
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
1 |
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|a Huang, Yue
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Regulating the Anode Corrosion by a Tryptophan Derivative for Alkaline Al-Air Batteries
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 02.05.2023
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|a Date Revised 02.05.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Screening a green corrosion inhibitor that can prevent Al anode corrosion and enhance the battery performance is highly significant for developing next-generation Al-air batteries. This work explores the non-toxic, environmentally safe, and nitrogen-rich amino acid derivative, N(α)-Boc-l-tryptophan (BCTO), as a green corrosion inhibitor for Al anodes. Our results confirm that BCTO has an excellent corrosion inhibition effect for the Al-5052 alloy in 4 M NaOH solution. An optimum inhibitor addition (2 mM) has increased the Al-air battery performance; the corrosion inhibition efficiency was 68.2%, and the anode utilization efficiency reached 92.0%. The capacity and energy density values increased from 990.10 mA h g-1 and 1317.23 W h kg-1 of the uninhibited system to 2739.70 mA h g-1 and 3723.53 W h kg-1 for the 2 mM BCTO added system. The adsorption behavior of BCTO on the Al-5052 surface was further explored by theoretical calculations. This work paves the way for constructing durable Al-air batteries through an electrolyte regulation strategy
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|a Journal Article
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1 |
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|a Guo, Lei
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhang, Qiao
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Shi, Wei
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Feng, Wei
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Abbas, Faheem
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zheng, Xingwen
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Leng, Senlin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Qiang, Yujie
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Saji, Viswanathan S
|e verfasserin
|4 aut
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| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 39(2023), 17 vom: 02. Mai, Seite 6018-6028
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
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|g volume:39
|g year:2023
|g number:17
|g day:02
|g month:05
|g pages:6018-6028
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|u http://dx.doi.org/10.1021/acs.langmuir.3c00032
|3 Volltext
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