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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.3c00256
|2 doi
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|a eng
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| 100 |
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|a Shimizu, Seishi
|e verfasserin
|4 aut
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|a Understanding Sorption Mechanisms Directly from Isotherms
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 02.05.2023
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|a Date Revised 06.05.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Currently, more than 100 isotherm models coexist for the six IUPAC isotherm types. However, no mechanistic insights can be reached when several models, each claiming a different mechanism, fit an experimental isotherm equally well. More frequently, popular isotherm models [such as the site-specific models like Langmuir, Brunauer-Emmett-Teller (BET), and Guggenheim-Anderson-de Boer (GAB)] have been applied to real and complex systems that break their basic assumptions. To overcome such conundrums, we establish a universal approach to model all isotherm types, attributing the difference to the sorbate-sorbate and sorbate-surface interactions in a systematic manner. We have generalized the language of the traditional sorption models (such as the monolayer capacity and the BET constant) to the model-free concepts of partitioning and association coefficients that can be applied across the isotherm types. Through such a generalization, the apparent contradictions, caused by applying the site-specific models alongside with cross-sectional area of sorbates for the purpose of surface area determination, can be eliminated straightforwardly
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|a Journal Article
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|a Matubayasi, Nobuyuki
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 39(2023), 17 vom: 02. Mai, Seite 6113-6125
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|x 1520-5827
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|g volume:39
|g year:2023
|g number:17
|g day:02
|g month:05
|g pages:6113-6125
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|u http://dx.doi.org/10.1021/acs.langmuir.3c00256
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