Mixed Matrix Membranes with Surface Functionalized Metal-Organic Framework Sieves for Efficient Propylene/Propane Separation
© 2023 The Authors. Advanced Materials published by Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 25 vom: 12. Juni, Seite e2300296 |
|---|---|
| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , , , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2023
|
| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article interfacial design metal-organic frameworks mixed matrix membranes propylene/propane separation |
| Zusammenfassung: | © 2023 The Authors. Advanced Materials published by Wiley-VCH GmbH. Membrane technology, regarded as an environmentally friendly and sustainable approach, offers great potential to address the large energy penalty associated with the energy-intensive propylene/propane separation. Quest for molecular sieving membranes for this important separation is of tremendous interest. Here, a fluorinated metal-organic framework (MOF) material, known as KAUST-7 (KAUST: King Abdullah University of Science and Technology) with well-defined narrow 1D channels that can effectively discriminate propylene from propane based on a size-sieving mechanism, is successfully incorporated into a polyimide matrix to fabricate molecular sieving mixed matrix membranes (MMMs). Markedly, the surface functionalization of KAUST-7 nanoparticles with carbene moieties affords the requisite interfacial compatibility, with minimal nonselective defects at polymer-filler interfaces, for the fabrication of a molecular sieving MMM. The optimal membrane with a high MOF loading (up to 45 wt.%) displays a propylene permeability of ≈95 barrer and a mixed propylene/propane selectivity of ≈20, far exceeding the state-of-the-art upper bound limits. Moreover, the resultant membrane exhibits robust structural stability under practical conditions, including high pressures (up to 8 bar) and temperatures (up to 100 °C). The observed outstanding performance attests to the importance of surface engineering for the preparation and plausible deployment of high-performance MMMs for industrial applications |
|---|---|
| Beschreibung: | Date Completed 22.06.2023 Date Revised 22.06.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202300296 |