|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM355406748 |
| 003 |
DE-627 |
| 005 |
20231226064258.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2023 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202301088
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1184.xml
|
| 035 |
|
|
|a (DE-627)NLM355406748
|
| 035 |
|
|
|a (NLM)37036047
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Sun, Qi-Qi
|e verfasserin
|4 aut
|
| 245 |
1 |
2 |
|a A Sulfur Heterocyclic Quinone Cathode Towards High-Rate and Long-Cycle Aqueous Zn-Organic Batteries
|
| 264 |
|
1 |
|c 2023
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 01.06.2023
|
| 500 |
|
|
|a Date Revised 01.06.2023
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2023 Wiley-VCH GmbH.
|
| 520 |
|
|
|a Organic materials have attracted much attention in aqueous zinc-ion batteries (AZIBs) due to their sustainability and structure-designable, but their further development is hindered by the high solubility, poor conductivity, and low utilization of active groups, resulting in poor cycling stability, terrible rate capability, and low capacity. In order to solve these three major obstacles, a novel organic host, benzo[b]naphtho[2',3':5,6][1,4]dithiino[2,3-i]thianthrene-5,7,9,14,16,18-hexone (BNDTH), with abundant electroactive groups and stable extended π-conjugated structure is synthesized and composited with reduced graphene oxide (RGO) through a solvent exchange composition method to act as the cathode material for AZIBs. The well-designed BNDTH/RGO composite exhibits a high capacity of 296 mAh g-1 (nearly a full utilization of the active groups), superior rate capability of 120 mAh g-1 , and a long lifetime of 58 000 cycles with a capacity retention of 65% at 10 A g-1 . Such excellent performance can be attributed to the ingenious structural design of the active molecule, as well as the unique solvent exchange composition strategy that enables effective dispersion of excess charge on the active molecule during discharge/charge process. This work provides important insights for the rational design of organic cathode materials and has significant guidance for realizing ideal high performance in AZIBs
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Zn-ion batteries
|
| 650 |
|
4 |
|a Zn-organic batteries
|
| 650 |
|
4 |
|a carbonyl compound materials
|
| 650 |
|
4 |
|a organic electrodes
|
| 700 |
1 |
|
|a Sun, Tao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Du, Jia-Yi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Kai
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Xie, Hai-Ming
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Huang, Gang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Xin-Bo
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 22 vom: 10. Juni, Seite e2301088
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:35
|g year:2023
|g number:22
|g day:10
|g month:06
|g pages:e2301088
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202301088
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 35
|j 2023
|e 22
|b 10
|c 06
|h e2301088
|