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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202300350
|2 doi
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|a pubmed24n1183.xml
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|a (NLM)36990460
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|a DE-627
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|c DE-627
|e rakwb
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|a eng
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| 100 |
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|a Guo, Jun-Chen
|e verfasserin
|4 aut
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|a A Self-Reconfigured, Dual-Layered Artificial Interphase Toward High-Current-Density Quasi-Solid-State Lithium Metal Batteries
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 15.06.2023
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|a Date Revised 15.06.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2023 Wiley-VCH GmbH.
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|a The uncontrollable dendrite growth and unstable solid electrolyte interphase have long plagued the practical application of Li metal batteries. Herein, a dual-layered artificial interphase LiF/LiBO-Ag is demonstrated that is simultaneously reconfigured via an electrochemical process to stabilize the lithium anode. This dual-layered interphase consists of a heterogeneous LiF/LiBO glassy top layer with ultrafast Li-ion conductivity and lithiophilic Li-Ag alloy bottom layer, which synergistically regulates the dendrite-free Li deposition, even at high current densities. As a result, Li||Li symmetric cells with LiF/LiBO-Ag interphase achieve an ultralong lifespan (4500 h) at an ultrahigh current density and area capacity (20 mA cm-2 , 20 mAh cm-2 ). LiF/LiBO-AgLi anodes are successfully applied in quasi-solid-state batteries, showing excellent cycling performances in symmetric cells (8 mA cm-2 , 8 mAh cm-2 , 5000 h) and full cells. Furthermore, a practical quasi-solid-state pouch cell coupling with a high-nickel cathode exhibits stable cycling with a capacity retention of over 91% after 60 cycles at 0.5 C, which is comparable or even better than that in liquid-state pouch cells. Additionally, a high-energy-density quasi-solid-state pouch cell (10.75 Ah, 448.7 Wh kg-1 ) is successfully accomplished. This well-orchestrated interphase design provides new guidance in engineering highly stable interphase toward practical high-energy-density lithium metal batteries
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|a Journal Article
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|a Li-ion transportation
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|a artificial solid electrolyte interphase
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|a lithiophilicity
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|a lithium metal
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|a rechargeable batteries
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| 700 |
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|a Tan, Shuang-Jie
|e verfasserin
|4 aut
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|a Zhang, Chao-Hui
|e verfasserin
|4 aut
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|a Wang, Wen-Peng
|e verfasserin
|4 aut
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| 700 |
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|a Zhao, Yao
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wang, Fuyi
|e verfasserin
|4 aut
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1 |
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|a Zhang, Xu-Sheng
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wen, Rui
|e verfasserin
|4 aut
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1 |
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|a Zhang, Ying
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Fan, Min
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Xin, Sen
|e verfasserin
|4 aut
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| 700 |
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|a Zhang, Juan
|e verfasserin
|4 aut
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| 700 |
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|a Guo, Yu-Guo
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 24 vom: 11. Juni, Seite e2300350
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:35
|g year:2023
|g number:24
|g day:11
|g month:06
|g pages:e2300350
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|u http://dx.doi.org/10.1002/adma.202300350
|3 Volltext
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