Calcium enhances phosphorus reclamation during biochar formation : Mechanisms and potential application as a phosphorus fertilizer in a paddy soil

Copyright © 2023 Elsevier Ltd. All rights reserved.

Bibliographische Detailangaben
Veröffentlicht in:Waste management (New York, N.Y.). - 1999. - 162(2023) vom: 01. Mai, Seite 83-91
1. Verfasser: Nan, Hongyan (VerfasserIn)
Weitere Verfasser: Yang, Fan, Li, Deping, Cao, Xinde, Xu, Xiaoyun, Qiu, Hao, Zhao, Ling
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Waste management (New York, N.Y.)
Schlagworte:Journal Article Ca(5)(PO(4))(3)Cl and Ca(10)(PO(4))(6)(OH)(2) crystals Paddy soil Phosphorus reclamation Phosphorus uptake Pyrolytic transformation Rice root and stalk Phosphorus 27YLU75U4W Calcium mehr... SY7Q814VUP biochar Fertilizers Soil Soil Pollutants Phosphates Charcoal 16291-96-6 Sewage
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245 1 0 |a Calcium enhances phosphorus reclamation during biochar formation  |b Mechanisms and potential application as a phosphorus fertilizer in a paddy soil 
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520 |a Transformation of phosphorus (P) species during pyrolytic production of biochar from P-rich biowastes with a subsequent soil amendment is important to P reclamation. Aiming at increasing the content of plant-available P and restraining the formation of easily mobile P in pyrolysis product, this study used exogenous calcium ions (20 wt% CaCl2) addition prior to pyrolysis to regulate the pyrolytic transformation of P chemical fractions from sewage sludge and bone dreg. Results showed that active Ca catalyzed the decomposition of organic P to transform into inorganic orthophosphate. Based on Hedley's sequential extraction method, this study found that addition of Ca ions remarkably reduced the content of soluble P, exchange P, Fe/Al bound P, and occluded P in biochar, while increased Ca bound P from 78 to 85% to 85-96%. Liquid 31P NMR indicated that exogenous Ca induced the crack of the P-O-P bond in pyrophosphate to become orthophosphates. It also explained why new orthophosphates including chlorapatite (Ca5(PO4)3Cl) and calcium hydroxyapatite (Ca10(PO4)6(OH)2) appeared in the Ca-composite biochar compared to pristine biochar. Combined with rapid P-release test in paddy soil (pH 6.27) and 30-days rice seedling growth test under flooded condition (10 wt% biochar addition ratio), it was confirmed that compared to pristine biochar, Ca-composite biochar released more P in paddy soil, but also promoted more P to be taken in by rice root and stalk. These results suggested that pretreating biowaste with Ca ion was a friendly approach to enhance P reclamation during biochar formation, making it a promising P fertilizer 
650 4 |a Journal Article 
650 4 |a Ca(5)(PO(4))(3)Cl and Ca(10)(PO(4))(6)(OH)(2) crystals 
650 4 |a Paddy soil 
650 4 |a Phosphorus reclamation 
650 4 |a Phosphorus uptake 
650 4 |a Pyrolytic transformation 
650 4 |a Rice root and stalk 
650 7 |a Phosphorus  |2 NLM 
650 7 |a 27YLU75U4W  |2 NLM 
650 7 |a Calcium  |2 NLM 
650 7 |a SY7Q814VUP  |2 NLM 
650 7 |a biochar  |2 NLM 
650 7 |a Fertilizers  |2 NLM 
650 7 |a Soil  |2 NLM 
650 7 |a Soil Pollutants  |2 NLM 
650 7 |a Phosphates  |2 NLM 
650 7 |a Charcoal  |2 NLM 
650 7 |a 16291-96-6  |2 NLM 
650 7 |a Sewage  |2 NLM 
700 1 |a Yang, Fan  |e verfasserin  |4 aut 
700 1 |a Li, Deping  |e verfasserin  |4 aut 
700 1 |a Cao, Xinde  |e verfasserin  |4 aut 
700 1 |a Xu, Xiaoyun  |e verfasserin  |4 aut 
700 1 |a Qiu, Hao  |e verfasserin  |4 aut 
700 1 |a Zhao, Ling  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Waste management (New York, N.Y.)  |d 1999  |g 162(2023) vom: 01. Mai, Seite 83-91  |w (DE-627)NLM098197061  |x 1879-2456  |7 nnns 
773 1 8 |g volume:162  |g year:2023  |g day:01  |g month:05  |g pages:83-91 
856 4 0 |u http://dx.doi.org/10.1016/j.wasman.2023.03.018  |3 Volltext 
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