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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1016/j.wasman.2023.03.018
|2 doi
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|a pubmed24n1181.xml
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|a (DE-627)NLM354533312
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|a (NLM)36948116
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|a (PII)S0956-053X(23)00237-4
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Nan, Hongyan
|e verfasserin
|4 aut
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|a Calcium enhances phosphorus reclamation during biochar formation
|b Mechanisms and potential application as a phosphorus fertilizer in a paddy soil
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 04.04.2023
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|a Date Revised 04.04.2023
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Copyright © 2023 Elsevier Ltd. All rights reserved.
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|a Transformation of phosphorus (P) species during pyrolytic production of biochar from P-rich biowastes with a subsequent soil amendment is important to P reclamation. Aiming at increasing the content of plant-available P and restraining the formation of easily mobile P in pyrolysis product, this study used exogenous calcium ions (20 wt% CaCl2) addition prior to pyrolysis to regulate the pyrolytic transformation of P chemical fractions from sewage sludge and bone dreg. Results showed that active Ca catalyzed the decomposition of organic P to transform into inorganic orthophosphate. Based on Hedley's sequential extraction method, this study found that addition of Ca ions remarkably reduced the content of soluble P, exchange P, Fe/Al bound P, and occluded P in biochar, while increased Ca bound P from 78 to 85% to 85-96%. Liquid 31P NMR indicated that exogenous Ca induced the crack of the P-O-P bond in pyrophosphate to become orthophosphates. It also explained why new orthophosphates including chlorapatite (Ca5(PO4)3Cl) and calcium hydroxyapatite (Ca10(PO4)6(OH)2) appeared in the Ca-composite biochar compared to pristine biochar. Combined with rapid P-release test in paddy soil (pH 6.27) and 30-days rice seedling growth test under flooded condition (10 wt% biochar addition ratio), it was confirmed that compared to pristine biochar, Ca-composite biochar released more P in paddy soil, but also promoted more P to be taken in by rice root and stalk. These results suggested that pretreating biowaste with Ca ion was a friendly approach to enhance P reclamation during biochar formation, making it a promising P fertilizer
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|a Journal Article
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|a Ca(5)(PO(4))(3)Cl and Ca(10)(PO(4))(6)(OH)(2) crystals
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|a Paddy soil
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|a Phosphorus reclamation
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|a Phosphorus uptake
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|a Pyrolytic transformation
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|a Rice root and stalk
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|a Phosphorus
|2 NLM
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|a 27YLU75U4W
|2 NLM
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|a Calcium
|2 NLM
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|a SY7Q814VUP
|2 NLM
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|a biochar
|2 NLM
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|a Fertilizers
|2 NLM
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|a Soil
|2 NLM
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|a Soil Pollutants
|2 NLM
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|a Phosphates
|2 NLM
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|a Charcoal
|2 NLM
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|a 16291-96-6
|2 NLM
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|a Sewage
|2 NLM
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|a Yang, Fan
|e verfasserin
|4 aut
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|a Li, Deping
|e verfasserin
|4 aut
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|a Cao, Xinde
|e verfasserin
|4 aut
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|a Xu, Xiaoyun
|e verfasserin
|4 aut
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|a Qiu, Hao
|e verfasserin
|4 aut
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|a Zhao, Ling
|e verfasserin
|4 aut
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|i Enthalten in
|t Waste management (New York, N.Y.)
|d 1999
|g 162(2023) vom: 01. Mai, Seite 83-91
|w (DE-627)NLM098197061
|x 1879-2456
|7 nnns
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|g volume:162
|g year:2023
|g day:01
|g month:05
|g pages:83-91
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|u http://dx.doi.org/10.1016/j.wasman.2023.03.018
|3 Volltext
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|a GBV_ILN_350
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|a AR
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|d 162
|j 2023
|b 01
|c 05
|h 83-91
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