|
|
|
|
| LEADER |
01000caa a22002652c 4500 |
| 001 |
NLM354374427 |
| 003 |
DE-627 |
| 005 |
20250304132306.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2023 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202209552
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n1180.xml
|
| 035 |
|
|
|a (DE-627)NLM354374427
|
| 035 |
|
|
|a (NLM)36932043
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Song, Junsheng
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Asymmetrically Coordinated CoB1 N3 Moieties for Selective Generation of High-Valence Co-Oxo Species via Coupled Electron-Proton Transfer in Fenton-like Reactions
|
| 264 |
|
1 |
|c 2023
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 08.06.2023
|
| 500 |
|
|
|a Date Revised 08.06.2023
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2023 The Authors. Advanced Materials published by Wiley-VCH GmbH.
|
| 520 |
|
|
|a High-valence metal species generated in peroxymonosulfate (PMS)-based Fenton-like processes are promising candidates for selective degradation of contaminants in water, the formation of which necessitates the cleavage of OH and OO bonds as well as efficient electron transfer. However, the high dissociation energy of OH bond makes its cleavage quite challenging, largely hampering the selective generation of reactive oxygen species. Herein, an asymmetrical configuration characterized by a single cobalt atom coordinated with boron and nitrogen (CoB1 N3 ) is established to offer a strong local electric field, upon which the cleavage of OH bond is thermodynamically favored via a promoted coupled electron-proton transfer process, which serves an essential step to further allow OO bond cleavage and efficient electron transfer. Accordingly, the selective formation of Co(IV)O in a single-atom Co/PMS system enables highly efficient removal performance toward various organic pollutants. The proposed strategy also holds true in other heteroatom doping systems to configure asymmetric coordination, thus paving alternative pathways for specific reactive species conversion by rationalized design of catalysts at atomic level toward environmental applications and more
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Fenton-like reactions
|
| 650 |
|
4 |
|a asymmetric coordination
|
| 650 |
|
4 |
|a coupled electron-proton transfers
|
| 650 |
|
4 |
|a high-valence metal species
|
| 650 |
|
4 |
|a single-atom catalysts
|
| 700 |
1 |
|
|a Hou, Nannan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Xiaocheng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Antonietti, Markus
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Pengjun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ding, Rongrong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Song, Li
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Yang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Mu, Yang
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 23 vom: 16. Juni, Seite e2209552
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
|
| 773 |
1 |
8 |
|g volume:35
|g year:2023
|g number:23
|g day:16
|g month:06
|g pages:e2209552
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202209552
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 35
|j 2023
|e 23
|b 16
|c 06
|h e2209552
|