Electrolytes with Solvating Inner Sheath Engineering for Practical Na-S Batteries
© 2023 Wiley-VCH GmbH.
Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 24 vom: 15. Juni, Seite e2300841 |
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1. Verfasser: | |
Weitere Verfasser: | , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2023
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Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
Schlagworte: | Journal Article electrolyte regulation sodium sulfur batteries sodium-metal anode solid-electrolyte interface solvation structure |
Zusammenfassung: | © 2023 Wiley-VCH GmbH. Sodium-sulfur (Na-S) batteries with durable Na-metal stability, shuttle-free cyclability, and long lifespan are promising to large-scale energy storages. However, meeting these stringent requirements poses huge challenges with the existing electrolytes. Herein, a localized saturated electrolyte (LSE) is proposed with 2-methyltetrahydrofuran (MeTHF) as an inner sheath solvent, which represents a new category of electrolyte for Na-S system. Unlike the traditional high concentration electrolytes, the LSE is realized with a low salt-to-solvent ratio and low diluent-to-solvent ratio, which pushes the limit of localized high concentration electrolyte (LHCE). The appropriate molecular structure and solvation ability of MeTHF regulate a saturated inner sheath, which features a reinforced coordination of Na+ to anions, enlarged Na+ -solvent distance, and weakened anion-diluent interaction. Such electrolyte configuration is found to be the key to build a sustainable interphase and a quasi-solid-solid sulfur redox process, making a dendrite-inhibited and shuttle-free Na-S battery possible. With this electrolyte, pouch cells with decent cycling performance under rather demanding conditions are demonstrated |
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Beschreibung: | Date Completed 15.06.2023 Date Revised 15.06.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
ISSN: | 1521-4095 |
DOI: | 10.1002/adma.202300841 |